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A facile "click" approach to functionalised metallosupramolecular architectures
被引:65
|作者:
Lewis, James E. M.
[1
]
McAdam, C. John
[1
]
Gardiner, Michael G.
[2
]
Crowley, James D.
[1
]
机构:
[1] Univ Otago, Dept Chem, Dunedin, New Zealand
[2] Univ Tasmania, Sch Chem, Hobart, Tas, Australia
关键词:
SPIN-CROSSOVER BEHAVIOR;
ORGANOPLATINUM(II) METALLACYCLES;
HEXAGONAL PRISMS;
DRUG-DELIVERY;
COMPLEXES;
CHEMISTRY;
HOSTS;
CONSTRUCTION;
DISCRETE;
HELICATE;
D O I:
10.1039/c3cc41209a
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Herein we describe a CuAAC "click" methodology for exo-functionalisation of Pd2L4 metallosupramolecular architectures. The potentially coordinating 1,2,3-triazole does not affect formation of the desired discrete complexes, nor does this external functional decoration affect the cisplatin-binding ability of the interior cavity of the assembly.
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页码:3398 / 3400
页数:3
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