Ion-solvent and ion-ion interactions of some tetraalkylammonium, alkali metals and ammonium halides in isoamyl alcohol at 298.25 K by conductometiric technique

被引：0

作者：

Roy, MN ^{[1
]}

Sinha, A ^{[1
]}

机构：

[1] N Bengal Univ, Dept Chem, Darjeeling 734013, W Bengal, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2006年 / 83卷 / 02期

关键词：

ion-solvated interaction; ion-ion interaction; conductometry;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Precise conductance measurements are reported for tetramethylammonium chloride (Me4NCl), tetraethylammonium bromide (Et4NBr), tetra propylammonium bromide (Pr4NBr), tetrabutylammonium bromide (Bu4NBr), tetrabutylammonium iodide (BU4NI), lithium bromide (LiBr), sodium iodide (NaI) and ammonium bromide (NH4Br) in isoamyl alcohol at 298.15 K. The conductance data have been analyzed by the Fuoss conductance-concentration equation in terms of the limiting molar conductance (Lambda(0)), the association constant (K-A) and the distance of the closest approach of ions (R). The results have been explained in terms of ion-solvent and ion-ion interactions.

引用

页码：160 / 164

页数：5