Synthesis of Co3O4@SnO2@C core-shell nanorods with superior reversible lithium-ion storage

被引:42
作者
Qi, Yue [1 ]
Zhang, Hui
Du, Ning
Zhai, Chuanxin
Yang, Deren
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
关键词
CO3O4; NANOTUBES; ANODE MATERIALS; CARBON SPHERES; ARRAYS; PERFORMANCE; CHALLENGES; NANOWIRES; BATTERIES;
D O I
10.1039/c2ra21765a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper describes a facile hydrothermal and subsequent carbonization approach for the synthesis of Co3O4@SnO2@C core-shell nanorods. The as-synthesized Co3O4@SnO2@ C nanorods have been applied as anode materials for lithium-ion batteries, which exhibit improved cyclic performance and enhanced power capability. Both Co3O4 and SnO2 are electrochemically active materials, and the hybridization of Co3O4 and SnO2 into an integrated core-shell nanorod structure makes them an elegant synergistic effect when participating in the lithium-ion charge-discharge process. In addition, the carbon matrix has good volume buffering effect and high electronic conductivity, which may be responsible for the improved electrochemical performance.
引用
收藏
页码:9511 / 9516
页数:6
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