Detecting and Quantifying Toxic Industrial Compounds (TICs) with Proton-Transfer-Reaction Mass Spectrometry (PTR-MS)

被引:0
作者
Kassebacher, Thomas [1 ,2 ]
Sulzer, Philipp [1 ]
Juerschik, Simone [1 ]
Agarwal, Bishu [2 ]
Petersson, Fredrik [1 ]
Hartungen, Eugen [1 ]
Seehauser, Hans [1 ]
Maerk, Tilmann D. [1 ,2 ]
机构
[1] IONICON Analyt GmbH, Eduard Bodem Gasse 3, A-6020 Innsbruck, Austria
[2] Leopold Franzens Univ Innsbruck, Inst Ionenphys & Angew Phys, A-6020 Innsbruck, Austria
来源
FUTURE SECURITY | 2012年 / 318卷
关键词
Toxic Industrial Compounds; TICs; Proton-Transfer-Reaction Mass Spectrometry; PTR-MS; PTR-TOFMS; threat detection;
D O I
暂无
中图分类号
TP301 [理论、方法];
学科分类号
081202 ;
摘要
In the course of the FP7-SEC project "SPIRIT" (Safety and Protection of built Infrastructure to Resist Integral Threats) we focused our research with Proton-Transfer-Reaction Mass Spectrometry (PTR-MS) on C-agents, specifically Toxic Industrial Compounds (TICs). Most TICs are readily available and represent a considerable threat when used in terroristic attacks. We show the principal procedure of PTR-MS detection measurements on two chemicals, namely phosgene and chloroacetone. With studies of the former we want to point out principle differences between measurements on a quadrupole mass filter based and a Time-of-Flight-based PTR-MS instrument and point out the respective benefits and drawbacks. For the latter we present the results of a diluted headspace measurement and illustrate the connection with security standards in buildings.
引用
收藏
页码:438 / +
页数:3
相关论文
共 10 条
[1]  
Biasioli F., 2011, TRENDS ANAL CHEM, V30
[2]  
Biasioli F., 2011, TRENDS ANAL CHEM, V30
[3]   Proton-Transfer Reaction Mass Spectrometry [J].
Blake, Robert S. ;
Monks, Paul S. ;
Ellis, Andrew M. .
CHEMICAL REVIEWS, 2009, 109 (03) :861-896
[4]   Detection of Plant Volatiles after Leaf Wounding and Darkening by Proton Transfer Reaction "Time-of-Flight" Mass Spectrometry (PTR-TOF) [J].
Brilli, Federico ;
Ruuskanen, Taina M. ;
Schnitzhofer, Ralf ;
Mueller, Markus ;
Breitenlechner, Martin ;
Bittner, Vinzenz ;
Wohlfahrt, Georg ;
Loreto, Francesco ;
Hansel, Armin .
PLOS ONE, 2011, 6 (05)
[5]  
Fatah A. A., 2001, GUIDE SELECTION CHEM, V1
[6]   On-line breath analysis with PTR-TOF [J].
Herbig, Jens ;
Mueller, Markus ;
Schallhart, Simon ;
Titzmann, Thorsten ;
Graus, Martin ;
Hansel, Armin .
JOURNAL OF BREATH RESEARCH, 2009, 3 (02)
[7]   A high resolution and high sensitivity proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS) [J].
Jordan, A. ;
Haidacher, S. ;
Hanel, G. ;
Hartungen, E. ;
Maerk, L. ;
Seehauser, H. ;
Schottkowsky, R. ;
Sulzer, P. ;
Maerk, T. D. .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2009, 286 (2-3) :122-128
[8]   An online ultra-high sensitivity Proton-transfer-reaction mass-spectrometer combined with switchable reagent ion capability (PTR+SRI-MS) [J].
Jordan, A. ;
Haidacher, S. ;
Hanel, G. ;
Hartungen, E. ;
Herbig, J. ;
Maerk, L. ;
Schottkowsky, R. ;
Seehauser, H. ;
Sulzer, P. ;
Maerk, T. D. .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2009, 286 (01) :32-38
[9]   Real-time trace detection and identification of chemical warfare agent simulants using recent advances in proton transfer reaction time-of-flight mass spectrometry [J].
Petersson, Fredrik ;
Sulzer, Philipp ;
Mayhew, Chris A. ;
Watts, Peter ;
Jordan, Alfons ;
Maerk, Lukas ;
Maerk, Tilmann D. .
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2009, 23 (23) :3875-3880
[10]   Reaction of ethyl 4,4,4-trifluoroacetoacetate enolate with 3-bromo-1,1,1-trifluoroacetone: Synthesis of 2,4-bis(trifluoromethyl)furan [J].
Smith, JO ;
Mandal, BK ;
Filler, R ;
Beery, JW .
JOURNAL OF FLUORINE CHEMISTRY, 1997, 81 (02) :123-128