Coordination-Like Chemistry of Phosphinidenes by Phosphanes

被引:57
作者
Protasiewicz, John D. [1 ]
机构
[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA
基金
美国国家科学基金会;
关键词
Phosphinidenes; Phosphorus; Coordination modes; Phosphanes; Phosphanylidenephosphoranes; P-RICH PHOSPHANES; MAIN-GROUP ELEMENTS; PHOSPHORUS CENTERS; DOUBLE-BOND; PHOSPHINOPHOSPHINIDENE (BU2P)-BU-T-P; STRUCTURAL-CHARACTERIZATION; 1,3-SILYL MIGRATION; CARBONYL-COMPOUNDS; CRYSTAL-STRUCTURE; WITTIG REACTION;
D O I
10.1002/ejic.201200273
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This microreview examines chemistry of phosphane adducts of phosphinidenes (phosphanylidene-s4-phosphoranes, RP=PR3) whose formation or reactions are reminiscent of the coordination chemistry of phosphane ligands in transition metal complexes.
引用
收藏
页码:4539 / 4549
页数:11
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