Formation of ternary lithium oxide-nickel oxide-magnesium oxide solid solution the Li/Ni/MgO system

被引:12
作者
Antolini, E [1 ]
机构
[1] Scuola Sci Mat, I-16016 Genoa, Italy
关键词
lithium oxide; nickel oxide; magnesium oxide; solid solutions;
D O I
10.1016/S0167-577X(01)00325-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of the thermal treatment at 1000 degreesC in air of Li/Ni/MgO system was investigated by X-ray diffraction (XRD) analysis. During air calcinations of Li/Ni/MgO system, the formation of a ternary LiyNixMg1-y-xO solid solution takes place. The presence of Ni3+ ions, as charge-compensating species, allows the incorporation of a high amount of Li+ ions into MgO lattice without the formation of oxygen vacancies. (C) 2001 Elsevier Science BY. All rights reserved.
引用
收藏
页码:385 / 388
页数:4
相关论文
共 17 条
  • [1] Low temperature hydrocracking of hydrocarbons on Ni-supported catalysts
    Akhmedov, VM
    Al-Khowaiter, SH
    Akhmedov, E
    Sadikhov, A
    [J]. APPLIED CATALYSIS A-GENERAL, 1999, 181 (01) : 51 - 61
  • [2] ON THE ROLE OF LITHIUM-CARBONATE IN THE PREPARATION OF DOPED NICKEL-OXIDE CATHODES FOR MOLTEN CARBONATE FUEL-CELLS
    ANTOLINI, E
    LEONINI, M
    MASSAROTTI, V
    MARINI, A
    BERBENNI, V
    CAPSONI, D
    [J]. SOLID STATE IONICS, 1990, 39 (3-4) : 251 - 261
  • [3] Antolini E, 1999, PHYS STATUS SOLIDI A, V173, P357, DOI 10.1002/(SICI)1521-396X(199906)173:2<357::AID-PSSA357>3.0.CO
  • [4] 2-A
  • [5] Structural change of LixNi1-xO during synthesis
    Antolini, E
    Ferretti, M
    [J]. MATERIALS LETTERS, 1997, 30 (01) : 59 - 63
  • [6] Effect of calcination on the structure of Ni/MgO catalyst: An x-ray diffraction study
    Arena, F
    Frusteri, F
    Parmaliana, A
    Plyasova, L
    Shmakov, AN
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (03): : 469 - 471
  • [7] Alkali promotion of Ni/MgO catalysts
    Arena, F
    Frusteri, F
    Parmaliana, A
    [J]. APPLIED CATALYSIS A-GENERAL, 1999, 187 (01) : 127 - 140
  • [8] CHARACTERIZATION OF LI-DOPED NI/MGO CATALYSTS
    ARENA, F
    CHUVILIN, AL
    PARMALIANA, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (03) : 990 - 998
  • [9] Solid-state interactions in Li-doped Ni/MgO catalysts
    Arena, F
    Frusteri, F
    Plyasova, L
    Parmaliana, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (22): : 3385 - 3391
  • [10] ARENA F, 1990, CATAL LETT, V6, P131