Bis{methyl Nβ-[4-(dipropylamino)benzylidene]dithiocarbazato}nickel(II)

被引：4
|
作者：
Fun, HK [1 ]
Chantrapromma, S
Razak, IA
Usman, A
Tang, YW
Ma, W
Wu, JY
Tian, YP
机构：
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[2] Anhui Univ, Dept Chem, Hefei 230039, Anhui, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[4] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801016397
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Schiff base ligand in the title complex, [Ni(C15H22N3S2)(2)], lost a proton from its tautomeric thiol form and coordinated to Ni(II) via the mercapto S and beta -N atoms. The geometry around the Ni atom is square planar with two equivalent Ni-N and Ni-S bonds. The two phenyl rings and the coordination moieties are in one plane forming an extensive electronic delocalization system. The structure is governed by C-H . . .S and C-H . . .N hydrogen bonds, leading to the formation of centrosymmetric dimers.
引用
收藏
页码：M519 / M521
页数：3
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