Synthesis of the Benzoate Intercalated Layered Double Hydroxide of Nickel and Aluminum: Application of Mering's Rule

被引：7

作者：

Manohara, G. V. ^{[1
]}

Kamath, P. Vishnu ^{[1
]}

机构：

[1] Bangalore Univ, Dept Chem, Cent Coll, Bangalore 560056, Karnataka, India

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 02期

关键词：

ANIONIC CLAYS; TEREPHTHALATE; RELEASE; ACID; LDH;

D O I：

10.1002/zaac.201300275

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homogeneous precipitation from a mixed metal nitrate solution using benzamide as a hydrolysis agent results in the formation of a benzoate-intercalated layered double hydroxide of nickel and aluminum with a basal spacing of 15.6 Å. The alternation in the line widths of the basal reflections has been shown to arise by the random interstratification of a 8.8 Å phase with an altered orientation of the benzoate ions. This work is an illustration of the application of Mering's rules to model disorder in layered double hydroxides. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：434 / 438

页数：5

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