Preparation and characteristics of bentonite-zeolite adsorbent and its application in swine wastewater

被引:28
作者
Cao, Leipeng [1 ]
Li, Zihan [1 ]
Xiang, Shuyu [1 ]
Huang, Zhenghua [1 ]
Ruan, Roger [1 ,2 ,3 ]
Liu, Yuhuan [1 ]
机构
[1] Nanchang Univ, Engn Res Ctr Biomass Convers, Minist Educ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China
[2] Univ Minnesota, Ctr Biorefining, Paul, MN 55108 USA
[3] Univ Minnesota, Dept Bioprod & Biosyst Engn, Paul, MN 55108 USA
基金
中国国家自然科学基金;
关键词
Bentonite; Zeolite; Adsorption model; Heavy metal; Swine wastewater; METAL ION REMOVAL; HEAVY-METALS; INDUSTRIAL WASTEWATERS; NUTRIENT REMOVAL; AQUEOUS-SOLUTION; ADSORPTION; CLAY; CU2+; ZINC; CD2+;
D O I
10.1016/j.biortech.2019.03.043
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The preparation of bentonite-zeolite (BZ) adsorbent using bentonite, aluminate, and rice husk was conducted. The adsorption experiment was performed for the removal of Cu2+ and Zn2+ from aqueous solution in single and binary systems. Results showed that gasification of rice husk could effectively improve the specific surface area and pore volume. The optimum pH for Cu2+ and Zn2+ adsorption on BZ was pH 5.0. The pseudo-first order kinetic and Langmuir isotherm model of BZ were the optimal model for Cu2+ and Zn2+. According to Langmuir isotherm model, the maximum adsorption capacity value (q(m)) was 16.39 and 12.72 mg.g(-1) for Cu2+ and Zn2+, respectively. The adsorption affinity order of BZ in the binary solution was Cu2+ > Zn2+center dot NH4+-N concentration over 500 mg.L-1 significantly affected the adsorption capacity of BZ (P < 0.05). The adsorption capacity of BZ for Cu2+ and Zn2+ was higher than that artificial zeolite (AZ) and bentonite in SW.
引用
收藏
页码:448 / 455
页数:8
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