Sulfonated hollow sphere carbon as an efficient catalyst for acetalisation of glycerol

被引:63
|
作者
Wang, Liang [1 ,2 ]
Zhang, Jian [1 ]
Yang, Shuang [3 ]
Sun, Qi [1 ]
Zhu, Longfeng [2 ]
Wu, Qinming [1 ]
Zhang, Haiyan [2 ]
Meng, Xiangju [1 ]
Xiao, Feng-Shou [1 ]
机构
[1] Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[3] Jilin Univ, Dept Chem, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
AMORPHOUS-CARBON; CONVERSION; ZEOLITE; DEHYDRATION; GRAPHENE; SO3H; GAS;
D O I
10.1039/c3ta10956a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sulfonated hollow sphere carbon (HSC-SO3H) was synthesized from carbonization of a SiO2-polymer core-shell structure, followed by removal of the SiO2 core and sulfonation with chlorosulfonic acid. HSC-SO3H shows superior performances in acetalisation of glycerol, which is related to the hollow sphere carbon shell with rich microporosity for good mass transfer in the reaction.
引用
收藏
页码:9422 / 9426
页数:5
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