New chiral ferrocenyl building blocks for asymmetric reactions

被引：23

作者：

Schwink, L ^{[1
]}

Knochel, P ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 21期

关键词：

LITHIUM AMIDE BASES; TRANSITION-METAL COMPLEXES; ENANTIOSELECTIVE DEPROTONATION; HYDROGENATION; ALKYLATION; REDUCTION; AMINO; ACIDS; DERIVATIVES; ADDITIONS;

D O I：

10.1016/S0040-4039(97)00722-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new C-2-symmetrical ferrocenyl amines 2 and 3 are easily prepared starting from the ketones 4. Their utility is demonstrated for enantioselective deprotonation reactions and highly diastereoselective alkylations of the amides 7. (C) 1997 Elsevier Science Ltd.

引用

页码：3711 / 3714

页数：4

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