Parametrization of the radial distribution function of a Yukawa fluid

被引:23
作者
Henderson, D
Teran, LMY
Blum, L
机构
[1] UNIV AUTONOMA METROPOLITANA IZTAPALAPA,DEPT FIS,MEXICO CITY 09340,DF,MEXICO
[2] UNIV PUERTO RICO,DEPT PHYS,RIO PIEDRAS,PR 00931
关键词
equation of state; low density; mean spherical approximation; radial distribution function; Yukawa fluid;
D O I
10.1016/S0378-3812(96)03197-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
We give semi-empirical expressions for five terms in an inverse temperature expansion of the radial distribution function of a Yukawa fluid. The parameters in these terms are chosen to fit what we believe should be an accurate equation of state when either the energy or pressure routes is used. Thus, a measure of self consistency is achieved. The equation of state which is the basis of our fit is the inverse temperature expansion of the Yukawa fluid free energy, obtained from the mean spherical approximation but modified to give reasonable results at low densities. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:65 / 72
页数:8
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