Conductivity study on lithium bromide in propylene carbonate plus acetonitrile mixtures in dilute solutions from-35 to 75°C

被引：14

作者：

Barthel, J ^{[1
]}

Neueder, R ^{[1
]}

Rawytsch, P ^{[1
]}

Roch, H ^{[1
]}

机构：

[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1999年 / 471卷 / 01期

关键词：

electrolyte conductivity; lithium bromide; propylene carbonate plus acetonitrile mixtures; association constant;

D O I：

10.1016/S0022-0728(99)00278-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Viscosity, permittivity and density data of the mixed solvent system propylene carbonate + acetonitrile (0 less than or equal to x(PC) less than or equal to 1) at temperatures - 35 to 95 degrees C and molar conductivities of lithium bromide in these mixtures were determined at temperatures - 35 to 75 degrees C with equipment known to yield precise data. Limiting conductivities and association constants are discussed on the basis of chemical model calculations. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：78 / 87

页数：10

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