Recent Advances in Photocatalytic Functionalization of Quinoxalin-2-ones

被引:88
作者
Rostoll-Berenguer, Jaume [1 ]
Blay, Gonzalo [1 ]
Pedro, Jose R. [1 ]
Vila, Carlos [1 ]
机构
[1] Univ Valencia, Fac Quim, Dept Quim Organ, Dr Moliner 50, Valencia 46100, Spain
关键词
Quinoxalin-2-ones; Visible-light photocatalysis; Radicals; Synthetic methods; Photoredox catalysis; VISIBLE-LIGHT PHOTOREDOX; CYCLOBUTANONE OXIME ESTERS; SYNTHETIC APPLICATIONS; IMINYL RADICALS; EOSIN Y; QUINOXALIN-2(1H)-ONES; METAL; CATALYSIS; QUINOXALINONES; CHEMISTRY;
D O I
10.1002/ejoc.202000746
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Visible-light-mediated chemical reactions have become highly popular in the last ten years. This review covers the recent developments in visible-light photofunctionalization of quinoxalin-2-one derivatives. Reaction types have been categorized depending on the kind of bond formed: C-C, C-O, C-N, C-S, C-P, and C-X, with representative examples and discussion on the catalyst used providing insightful mechanistic details. Moreover, their applications to the synthesis of biologically active compounds has also been discussed.
引用
收藏
页码:6148 / 6172
页数:25
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