Ammonia and Hydrazine from Coordinated Dinitrogen by Complexes of Iron(0)

被引：6

作者：

Field, Leslie D. ^{[1
]}

Li, Hsiu L. ^{[1
]}

Dalgarno, Scott J. ^{[2
]}

McIntosh, Ruaraidh D. ^{[2
]}

机构：

[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Heriot Watt Univ, Sch EPS Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 14期

关键词：

Ammonia; Catalysis; Nitrogen fixation; Iron; Hydrazine; GRAPHITE INTERCALATION COMPOUNDS; HIGH-SPIN IRON(I); BIS(IMINO)PYRIDINE IRON; N-2-TO-NH3; CONVERSION; PINCER LIGANDS; REDUCTION; N-2; NITROGEN; HYDROGENATION; REACTIVITY;

D O I：

10.1002/ejic.201900058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron(0) dinitrogen complexes [Fe(N-2)(PP(3)A (R))] (PP(3)A (R) = P(CH2CH2PR2)(3), R = Ph, iPr, Cy) were synthesized by reduction of the precursor chloro complexes with potassium graphite. On reaction with triflic acid, [Fe(N-2)(PP(3)A (R))] complexes afforded ammonia and hydrazine in yields of up to 23 and 16 % respectively. The complex [Fe(N-2)(PP3Ph)] which has only been previously synthesized in situ, has now been isolated and fully characterized by N-15 NMR spectroscopy and by X-ray crystallography.

引用

页码：2006 / 2011

页数：6

共 59 条

[31] Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation [J].

Higuchi, Junichi ;

Kuriyama, Shogo ;

Eizawa, Aya ;

Arashiba, Kazuya ;

Nakajima, Kazunari ;

Nishibayashi, Yoshiaki .

DALTON TRANSACTIONS, 2018, 47 (04) :1117-1121

[32] Synthesis, structure and reactions of a dinitrogen complex of iron(0), [Fe(N-2)(depe)(2)] (depe equals Et2PCH2CH2PEt2) [J].

Hirano, M ;

Akita, M ;

Morikita, T ;

Kubo, H ;

Fukuoka, A ;

Komiya, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (19) :3453-3458

[33] USE OF THE NEW LIGAND P(CH2CH2PCY2)3 IN THE SYNTHESIS OF DIHYDROGEN COMPLEXES OF IRON(II) AND RUTHENIUM(II) [J].

JIA, GC ;

DROUIN, SD ;

JESSOP, PG ;

LOUGH, AJ ;

MORRIS, RH .

ORGANOMETALLICS, 1993, 12 (03) :906-916

[34] THE REDUCTION OF [FE(CO)(2)L(2)X(2)](L=P(OME)(3),P(OIPR)(3), PET(3), X=BR, I) - FROM IRON(II) TO IRON(0) VIA STABLE IRON(I) INTERMEDIATES [J].

KANDLER, H ;

GAUSS, C ;

BIDELL, W ;

ROSENBERGER, S ;

BURGI, T ;

EREMENKO, IL ;

VEGHINI, D ;

ORAMA, O ;

BURGER, P ;

BERKE, H .

CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (08) :541-548

[35] ISOLATION OF A ZEROVALENT IRON DINITROGEN COMPLEX WITH 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS [J].

KOMIYA, S ;

AKITA, M ;

YOZA, A ;

KASUGA, N ;

FUKUOKA, A ;

KAI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (09) :787-788

[36] Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand [J].

Kuriyama, Shogo ;

Arashiba, Kazuya ;

Nakajima, Kazunari ;

Matsuo, Yuki ;

Tanaka, Hiromasa ;

Ishii, Kazuyuki ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

NATURE COMMUNICATIONS, 2016, 7

[37]

Lee Y, 2010, NAT CHEM, V2, P558, DOI [10.1038/NCHEM.660, 10.1038/nchem.660]

[38]

Mankad N.P., 2007, ANGEW CHEM INT EDIT, V119, P5870

[39] Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands [J].

Mankad, Neal P. ;

Whited, Matthew T. ;

Peters, Jonas C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (30) :5768-5771

[40] A Terminal N2 Complex of High-Spin Iron(I) in a Weak, Trigonal Ligand Field [J].

McSkimming, Alex ;

Harman, W. Hill .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (28) :8940-8943

← 1 2 3 4 5 6 →