Ammonia and Hydrazine from Coordinated Dinitrogen by Complexes of Iron(0)

被引：6

作者：

Field, Leslie D. ^{[1
]}

Li, Hsiu L. ^{[1
]}

Dalgarno, Scott J. ^{[2
]}

McIntosh, Ruaraidh D. ^{[2
]}

机构：

[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Heriot Watt Univ, Sch EPS Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 14期

关键词：

Ammonia; Catalysis; Nitrogen fixation; Iron; Hydrazine; GRAPHITE INTERCALATION COMPOUNDS; HIGH-SPIN IRON(I); BIS(IMINO)PYRIDINE IRON; N-2-TO-NH3; CONVERSION; PINCER LIGANDS; REDUCTION; N-2; NITROGEN; HYDROGENATION; REACTIVITY;

D O I：

10.1002/ejic.201900058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron(0) dinitrogen complexes [Fe(N-2)(PP(3)A (R))] (PP(3)A (R) = P(CH2CH2PR2)(3), R = Ph, iPr, Cy) were synthesized by reduction of the precursor chloro complexes with potassium graphite. On reaction with triflic acid, [Fe(N-2)(PP(3)A (R))] complexes afforded ammonia and hydrazine in yields of up to 23 and 16 % respectively. The complex [Fe(N-2)(PP3Ph)] which has only been previously synthesized in situ, has now been isolated and fully characterized by N-15 NMR spectroscopy and by X-ray crystallography.

引用

页码：2006 / 2011

页数：6

共 59 条

[1] Catalytic conversion of nitrogen to ammonia by an iron model complex [J].

Anderson, John S. ;

Rittle, Jonathan ;

Peters, Jonas C. .

NATURE, 2013, 501 (7465) :84-+

[2]

[Anonymous], 2017, ANGEW CHEM

[3] Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation [J].

Archer, Andrew M. ;

Bouwkamp, Marco W. ;

Cortez, Maria-Patricia ;

Lobkovsky, Emil ;

Chirik, Paul J. .

ORGANOMETALLICS, 2006, 25 (18) :4269-4278

[4] Characterization of an Intermediate in the Ammonia-Forming Reaction of Fe(DMeOPrPE)2N2 with Acid (DMeOPrPE=1,2-[bis(dimethoxypropyl)phosphino]ethane) [J].

Balesdent, Chantal G. ;

Crossland, Justin L. ;

Regan, Daniel T. ;

Lopez, Coralys T. ;

Tyler, David R. .

INORGANIC CHEMISTRY, 2013, 52 (24) :14178-14187

[5] Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation [J].

Bart, SC ;

Lobkovsky, E ;

Chirik, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) :13794-13807

[6] Neutral-ligand complexes of bis(imino)pyridine iron: Synthesis, structure, and spectroscopy [J].

Bart, Suzanne C. ;

Lobkovsky, Emil ;

Bill, Eckhard ;

Wieghardt, Karl ;

Chirik, Paul J. .

INORGANIC CHEMISTRY, 2007, 46 (17) :7055-7063

[7] Anodically-induced metal deprotonation of the hydride complexes [{PCH2CH2PPh2)(3)}M(H)Cl] (M=Fe, Ru, Os): The first step to the electrogeneration of Fe(I), Ru(I) and Os(I) five-coordinate complexes [J].

Bianchini, C ;

Peruzzini, M ;

Ceccanti, A ;

Laschi, F ;

Zanello, P .

INORGANICA CHIMICA ACTA, 1997, 259 (1-2) :61-70

[8] TRIPODAL POLYPHOSPHINE LIGANDS CONTROL SELECTIVITY OF ORGANOMETALLIC REACTIONS [J].

BIANCHINI, C ;

MELI, A ;

PERUZZINI, M ;

VIZZA, F ;

ZANOBINI, F .

COORDINATION CHEMISTRY REVIEWS, 1992, 120 :193-208

[9] AN EXCEPTIONALLY STABLE CIS-(HYDRIDE)(ETA-2-DIHYDROGEN) COMPLEX OF IRON [J].

BIANCHINI, C ;

PERUZZINI, M ;

ZANOBINI, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (02) :C19-C22

[10] N2-to-NH3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis [J].

Buscagan, Trixia M. ;

Oyala, Paul H. ;

Peters, Jonas C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (24) :6921-6926

← 1 2 3 4 5 6 →