Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides

被引：43

作者：

Gusarova, Nina K. ^{[1
]}

Malysheva, Svetlana F. ^{[1
]}

Kuimov, Vladimir A. ^{[1
]}

Belogorlova, Nataliya A. ^{[1
]}

Mikhailenko, Valentina L. ^{[1
]}

Trofimov, Boris A. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

来源：

MENDELEEV COMMUNICATIONS | 2008年 / 18卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/j.mencom.2008.09.011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphine readily adds to 1-(tert-butyl)-4-vinylbenzene in the KOH-DMSO system (70-120 degrees C, 3 h, atmospheric pressure) to form bis[4-(tert-butyl)phenethyl]phosphine and tris[4-(tert-butyl)phenethyl]phosphine, which are further oxidized to corresponding phosphine oxides, sulfides and selenides.

引用

页码：260 / 261

页数：2

共 34 条

[1] Transition-metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes [J].

Alonso, F ;

Beletskaya, IP ;

Yus, M .

CHEMICAL REVIEWS, 2004, 104 (06) :3079-3159

[2] Nucleophilic and free-radical additions of phosphines and phosphine chalcogenides to alkenes and alkynes [J].

Arbuzova, Svetlana N. ;

Gusarova, Nina K. ;

Trofimov, Boris A. .

ARKIVOC, 2006, :12-36

[3] Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands [J].

Blann, K ;

Bollmann, A ;

Dixon, JT ;

Hess, FM ;

Killian, E ;

Maumela, H ;

Morgan, DH ;

Neveling, A ;

Otto, S ;

Overett, MJ .

CHEMICAL COMMUNICATIONS, 2005, (05) :620-621

[4] t-BuOK-catalyzed addition phosphines to functionalized alkenes:: a convenient synthesis of polyfunctional phosphine derivatives [J].

Bunlaksananusorn, T ;

Knochel, P .

TETRAHEDRON LETTERS, 2002, 43 (33) :5817-5819

[5] A facile, microwave-assisted, palladium-catalyzed arylation of acetone [J].

Chobanian, Harry R. ;

Liu, Ping ;

Chioda, Marc D. ;

Guo, Yan ;

Lin, Linus S. .

TETRAHEDRON LETTERS, 2007, 48 (07) :1213-1216

[6] Multiphase systems for the recychug of alkoxycarbonylation catalysts [J].

de Pater, Jeroen J. M. ;

Deelman, Berth-Jan ;

Elsevier, Cornelis J. ;

van Koten, Gerard .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (12-13) :1447-1458

[7] The phospha-Michael addition in organic synthesis [J].

Enders, D ;

Saint-Dizier, A ;

Lannou, MI ;

Lenzen, A .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (01) :29-49

[8]

Engel R., 2004, Synthesis of Carbon-Phosphorus Bonds, VSecond

[9]

FUJITA T, 1979, SYNTHESIS-STUTTGART, P310

[10] Preparation of a palladium dimer with a cobalt-containing bulky phosphine ligand: Its application in palladium catalyzed Suzuki reactions [J].

Gan, Ya-Huei ;

Lee, Han-Cheng ;

Hong, Fung-E. .

POLYHEDRON, 2006, 25 (18) :3555-3561

← 1 2 3 4 →