Estimation of 90Sr in reprocessing streams using pre-packed extraction chromatographic column of 4,4′(5′)-bis(tert-butylcyclohexano)-18-crown-6 impregnated on amberlite XAD-7

被引：3

作者：

Dileep, C. S. ^{[1
]}

Jagasia, Poonam ^{[2
]}

Das, S. K. ^{[1
]}

Dhami, Prem Singh ^{[1
]}

Tripathi, S. C. ^{[1
]}

Gandhi, P. M. ^{[1
]}

Tomar, B. S. ^{[3
]}

机构：

[1] Bhabha Atom Res Ctr, Fuel Reproc Div, Mumbai 400085, Maharashtra, India

[2] Bhabha Atom Res Ctr, Proc Dev Div, Mumbai 400085, Maharashtra, India

[3] Bhabha Atom Res Ctr, Radioanalyt Chem Div, Mumbai 400085, Maharashtra, India

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2013年 / 298卷 / 01期

关键词：

Sr-90; analysis; Extraction chromatography; 4,4 '(5 ')-bis(tert-butylcyclohexano)-18-crown-6; PUREX process; THOREX process; ACIDIC NITRATE MEDIA; STRONTIUM; Y-90;

D O I：

10.1007/s10967-013-2534-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This paper describes a method for the estimation of Sr-90 in various PUREX and THOREX process streams. Radiostrontium present in the sample is loaded on an extraction chromatographic column containing 4,4'(5')-bis(tert-butylcyclohexano)-18-crown-6 (DtBuCH18C6) in 1-octanol impregnated on amberlite XAD-7 after diluting it appropriately in about 3.0 M HNO3. The column is then washed using 3 M HNO3 to remove the impurities completely and finally Sr-90 is eluted in 5 mL of water and subjected to beta counting without time delay. Recovery of Sr-90 separation is studied in presence of varying quantity of uranium and thorium in the sample. The method is used to estimate Sr-90 in actual process samples containing Sr-90 activity in wide range of activity varying from Bq/mL to Ci/L. The results are compared with those obtained by conventional radiochemical precipitation method and found to agree within +/- 5 %.

引用

页码：105 / 110

页数：6

共 6 条

[1] Estimation of 90Sr in reprocessing streams using pre-packed extraction chromatographic column of 4,4'(5')-bis(tert-butylcyclohexano)-18-crown-6 impregnated on amberlite XAD-7
C. S. Dileep
Poonam Jagasia
S. K. Das
Prem Singh Dhami
S. C. Tripathi
P. M. Gandhi
B. S. Tomar
Journal of Radioanalytical and Nuclear Chemistry, 2013, 298 : 105 - 110
[2] Kinetics of the adsorption of strontium(II) by a novel silica-based 4,4′,(5′)-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium
A. Zhang
Y. -Z. Wei
M. Kumagai
T. Koyama
Journal of Radioanalytical and Nuclear Chemistry, 2005, 262 (3) : 739 - 744
[3] Kinetics of the adsorption of strontium(II) by a novel silica-based 4,4′,(5′)-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium
Zhang, A
Wei, YZ
Kumagai, M
Koyama, T
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2004, 262 (03) : 739 - 744
[4] Kinetics of the adsorption of strontium(II) by a novel silica-based 4,4',(5')-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium
A. Zhang
Y.-Z. Wei
M. Kumagai
T. Koyama
Journal of Radioanalytical and Nuclear Chemistry, 2004, 262 : 739 - 744
[5] Selective extraction of 90Sr in urine using 4′4"(5")di-tert-butyl dicyclohexano-18-crown-6 ether immobilized on polyacrylamide-coated magnetic nanoparticles
Varve, Zack
Lai, Edward P. C.
Li, Chunsheng
Sadi, Baki B.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2015, 303 (01) : 1053 - 1057
[6] Selective extraction of 90Sr in urine using 4′4″(5″)di-tert-butyl dicyclohexano-18-crown-6 ether immobilized on polyacrylamide-coated magnetic nanoparticles
Zack Varve
Edward P. C. Lai
Chunsheng Li
Baki B. Sadi
Journal of Radioanalytical and Nuclear Chemistry, 2015, 303 : 1053 - 1057

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