Transition Metal Frustrated Lewis Pairs

被引：132

作者：

Flynn, Stephanie R. ^{[1
]}

Wass, Duncan F. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol, Avon, England

来源：

ACS CATALYSIS | 2013年 / 3卷 / 11期

关键词：

frustrated Lewis pairs; cooperative effects; ligand-assisted reactions; small molecule activation; ASYMMETRIC TRANSFER HYDROGENATION; STEREOSELECTIVE HYDROGENATION; HETEROLYTIC CLEAVAGE; ELECTRONIC CONTROL; CARBON-MONOXIDE; BORANE ADDUCTS; IRON COMPLEX; ACTIVATION; REACTIVITY; CO2;

D O I：

10.1021/cs400754w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Frustrated Lewis pair chemistry, in which solution phase combinations of Lewis acid Lewis base pairs (FLPs) act cooperatively to activate small molecules, is one of the most exciting recent developments in main group chemistry. Far less developed but of growing interest are FLP systems containing transition metals as one of the Lewis acid/base components. This Perspective reviews recent developments in this area and makes connections to existing research into cooperative and ligand assisted catalysis.

引用

页码：2574 / 2581

页数：8

共 50 条

[41] Frustrated Lewis Pairs: Discovery and Overviews in Catalysis
Li, Nan
Zhang, Wen-Xiong
CHINESE JOURNAL OF CHEMISTRY, 2020, 38 (11) : 1360 - 1370
[42] Complexation of Nitrous Oxide by Frustrated Lewis Pairs
Otten, Edwin
Neu, Rebecca C.
Stephan, Douglas W.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (29) : 9918 - +
[43] Hydrogenation activity of Lewis acid-base pairs: A new theoretical model to understand the degradation of CO/CO2 catalyzed by Frustrated Lewis pairs
Liu, Zhengwu
Zhang, Yuan
Wang, Kun
Cheng, Longjiu
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 86 : 1129 - 1139
[44] Metal-Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with "Inverse" Frustrated Lewis Pairs
Durin, Gabriel
Berthet, Jean-Claude
Thuery, Pierre
Nicolas, Emmanuel
Cantat, Thibault
CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (61)
[45] The activity and reversibility of intramolecular B/N Frustrated Lewis Pairs in the hydrogenation
Mao, Hui
Chen, Zijiang
Cheng, Longjiu
Wang, Kun
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (01) : 110 - 118
[46] Reversible, metal-free hydrogen activation by frustrated Lewis pairs
Jiang, Chunfang
Blacque, Olivier
Fox, Thomas
Berke, Heinz
DALTON TRANSACTIONS, 2011, 40 (05) : 1091 - 1097
[47] Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules
Stephan, Douglas W.
FRUSTRATED LEWIS PAIRS I: UNCOVERING AND UNDERSTANDING, 2013, 332 : 1 - 44
[48] Unusual catalytic hydrogenation caused by photoinduced solid frustrated Lewis pairs
Wan, Zhen
Wang, Chengjun
Yang, Chun
Ma, Dongge
Ji, Hongwei
Chen, Chuncheng
Ma, Wanhong
Zhao, Jincai
APPLIED CATALYSIS B-ENVIRONMENTAL, 2023, 324
[49] Parallels between Metal-Ligand Cooperativity and Frustrated Lewis Pairs
Habraken, Evi R. M.
Jupp, Andrew R.
Brands, Maria B.
Nieger, Martin
Ehlers, Andreas W.
Slootweg, J. Chris
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (19) : 2436 - 2442
[50] Frustrated Lewis Pairs Bridged by Water and Immobilized in a Metal-Organic Framework as a Recyclable Transfer Hydrogenation Nanocatalyst
Xu, Hailong
Song, Xuedan
Chen, Miaomiao
Bai, Wei
Zhang, Jie
Ji, Min
ACS APPLIED NANO MATERIALS, 2023, 6 (07) : 5255 - 5263

← 1 2 3 4 5 →