Transition Metal Frustrated Lewis Pairs

被引：132
|
作者：
Flynn, Stephanie R. [1 ]
Wass, Duncan F. [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol, Avon, England
来源：
ACS CATALYSIS | 2013年 / 3卷 / 11期
关键词：
frustrated Lewis pairs; cooperative effects; ligand-assisted reactions; small molecule activation; ASYMMETRIC TRANSFER HYDROGENATION; STEREOSELECTIVE HYDROGENATION; HETEROLYTIC CLEAVAGE; ELECTRONIC CONTROL; CARBON-MONOXIDE; BORANE ADDUCTS; IRON COMPLEX; ACTIVATION; REACTIVITY; CO2;
D O I：
10.1021/cs400754w
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Frustrated Lewis pair chemistry, in which solution phase combinations of Lewis acid Lewis base pairs (FLPs) act cooperatively to activate small molecules, is one of the most exciting recent developments in main group chemistry. Far less developed but of growing interest are FLP systems containing transition metals as one of the Lewis acid/base components. This Perspective reviews recent developments in this area and makes connections to existing research into cooperative and ligand assisted catalysis.
引用
收藏
页码：2574 / 2581
页数：8
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