Direct Synthesis of Sorbitol and Glycerol from Cellulose over Ionic Ru/Magnetite Nanoparticles in the Absence of External Hydrogen

被引：20

作者：

Negoi, Alina ^{[1
]}

Trotus, Ioan Teodor ^{[1
,2
]}

Steiner, Olimpia Mamula ^{[2
]}

Tudorache, Madalina ^{[1
]}

Kuncser, Victor ^{[3
]}

Macovei, Dan ^{[3
]}

Parvulescu, Vasile I. ^{[1
]}

Coman, Simona M. ^{[1
]}

机构：

[1] Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, Bucharest 030016, Romania

[2] Univ Appl Sci Western Switzerland, Ecole Ingenieurs & Architectes Fribourg, CH-1705 Fribourg, Switzerland

[3] Natl Inst Mat Phys, Magurele 077125, Romania

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 11期

关键词：

carbohydrates; cellulose; iron; nanoparticles; ruthenium; CATALYTIC CONVERSION; RUTHENIUM; HYDROLYSIS; ALKANES;

D O I：

10.1002/cssc.201300554

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sweet catalyst: A catalyst formed of Ru/functionalized silica-coated magnetite nanoparticles is highly efficient in the one-pot production of sorbitol and glycerol, starting from cellulose and in the absence of an external hydrogen source. The ease of recoverability of the catalyst from the solid residues, and its reuse without loss of activity or selectivity for several runs, is an important green element of the process. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2090 / 2094

页数：5

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