Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate

被引：3
作者：
Chen, Yongle [1 ]
Ding, Shiya [1 ]
Zheng, Wentao [1 ]
Zhang, Yiyang [1 ]
Wu, Youting [1 ]
Hu, Xingbang [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, MOE, Key Lab Mesoscop Chem,Separat Engn Res Ctr, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2016年 / 37卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Geranyl acetate; Esterification; Kinetics; Proton gradient transfer; Reaction-induced self-separation catalyst; IONIC LIQUIDS; ESTERIFICATION; BIODIESEL; EFFICIENT; CARBON; TRANSESTERIFICATION; ACYLATION; ALCOHOLS; KINETICS;
D O I：
10.1016/S1872-2067(16)62577-9
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Special proton-gradient-transfer acid complexes (PGTACs) in which the bonded protons are not equivalent and have gradients in transfer ability, acidity, and reactivity were reported. The acidity gradient of the protons gave the PGTACs excellent catalytic activity and selectivity in the esterification of terpenols. These PGTACs are "reaction-induced self-separation catalysts" and can be easily reused. The kinetics with PGTACs as catalyst in the esterification of geraniol were also studied for use in engineering design. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：2114 / 2121
页数：8
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