Postsynthetic functionalization of 3D covalent organic frameworks

被引：108

作者：

Bunck, David N. ^{[1
]}

Dichtel, William R. ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 24期

基金：

美国国家科学基金会;

关键词：

TARGETED SYNTHESIS; CRYSTALLINE; CONSTRUCTION;

D O I：

10.1039/c3cc40358k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate a tandem truncation-functionalization strategy using the 3D covalent organic framework, COF-102. Allyl groups incorporated within the pore walls were subjected to thiol-ene coupling conditions, achieving high conversions and maintaining the crystallinity and permanent porosity of the parent framework.

引用

页码：2457 / 2459

页数：3

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