Titanocene-catalysed enantioselective opening of meso-epoxides

被引:1
|
作者
Gansäuer, A [1 ]
Bluhm, H [1 ]
Lauterbach, T [1 ]
机构
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-55121 Bonn, Germany
关键词
enantioselectivity; epoxides; diastereoselectivity; radical reactions; titanium;
D O I
10.1002/1615-4169(20011231)343:8<785::AID-ADSC785>3.0.CO;2-Q
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A comparison or different titanium catalysts in the enantioselective opening of meso-epoxides has been carried out. The best catalyst is readily available in both enantiomers from menthol and allows for a highly enantioselective reaction.
引用
收藏
页码:785 / 787
页数:3
相关论文
共 50 条
  • [1] Titanocene-catalysed electron transfer-mediated opening of epoxides
    Gansäuer, A
    Narayan, S
    ADVANCED SYNTHESIS & CATALYSIS, 2002, 344 (05) : 465 - 475
  • [2] A catalytic enantioselective electron transfer reaction:: Titanocene-catalyzed enantioselective formation of radicals from meso-epoxides
    Gansäuer, A
    Lauterbach, T
    Bluhm, H
    Noltemeyer, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (19) : 2909 - 2910
  • [3] Enantioselective Ring Opening of meso-Epoxides with Aromatic Amines Catalyzed by Dinuclear Magnesium Complexes
    Bao, Hongli
    Wang, Zheng
    You, Tianpa
    Ding, Kuiling
    CHINESE JOURNAL OF CHEMISTRY, 2013, 31 (01) : 67 - 71
  • [4] Highly enantioselective iron(II)-catalyzed opening reaction of aromatic meso-epoxides with indoles
    Plancq, Baptiste
    Lafantaisie, Mathieu
    Companys, Simon
    Maroun, Cendrella
    Ollevier, Thierry
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (43) : 7463 - 7466
  • [5] Vanadium-salan catalyzed enantioselective ring opening of meso-epoxides with aromatic amines
    Sun, Jiangtao
    Dai, Zhenya
    Yang, Minghua
    Pan, Xu
    Zhu, Chengjian
    SYNTHESIS-STUTTGART, 2008, (13): : 2100 - 2104
  • [6] Enantioselective ring opening of meso-epoxides by aromatic amines catalyzed by lanthanide iodo binaphtholates
    Carrée, F
    Gil, R
    Collin, J
    ORGANIC LETTERS, 2005, 7 (06) : 1023 - 1026
  • [7] Enantioselective alpha-deprotonation-rearrangement of meso-epoxides
    Hodgson, DM
    Lee, GP
    CHEMICAL COMMUNICATIONS, 1996, (09) : 1015 - 1016
  • [8] Chiral scandium-catalysed enantioselective ring-opening of meso-epoxides with N-heterocycle, alcohol and thiol derivatives in water
    Boudou, Marine
    Ogawa, Chikako
    Kobayashi, Shu
    ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (18) : 2585 - 2589
  • [9] Enantioselective ring opening of meso-epoxides with thiols catalyzed by a chiral (salen)Ti(IV) complex
    Wu, J
    Hou, XL
    Dai, LX
    Xia, LJ
    Tang, MH
    TETRAHEDRON-ASYMMETRY, 1998, 9 (19) : 3431 - 3436
  • [10] Scandium-bipyridine-catalyzed, enantioselective alcoholysis of meso-epoxides
    Tschoep, Andreas
    Marx, Andreas
    Sreekanth, Anakallil R.
    Schneider, Christoph
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (14) : 2318 - 2327