Pd/APN-Mn(BTC) as novel, highly efficient, and recyclable catalyst for Suzuki-Miyaura cross coupling reaction

被引:7
作者
Aliyan, Hamid [1 ]
Fazaeli, Razieh [1 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 86145311, Iran
关键词
Suzuki-Miyaura reaction; heterogeneous catalyst; Metal Organic Frameworks (MOFs); METAL-ORGANIC FRAMEWORK; HETEROGENEOUS CATALYST; PD NANOPARTICLES; BIODIESEL PRODUCTION; PALLADIUM CATALYST; OXIDATION; COMPLEX; ACID; HYDROGENATION; SILICA;
D O I
10.1139/cjc-2019-0320
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel, heterogeneous, and bifunctional metal organic framework containing palladium and manganese, Pd/APN-Mn(BTC), has been prepared and completely characterized using FTIR, XRD, SEM-EDS, N-2 adsorption-desorption, TG-DTG, NH3-TPD, and ICP analytical techniques. The APN-Mn(BTC) framework has been shown to be a useful platform for the stabilization and support of palladium nanoparticles (Pd NPs). Very effective catalytic activity has been exhibited by the highly dispersed Pd particles, Pd-NPs/APN-Mn(BTC), in the Suzuki-Miyaura cross-coupling reaction with reasonable to excellent reaction yields under mild conditions in H2O-ethanol solvent.
引用
收藏
页码:445 / 452
页数:8
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