Patterning of hydrogen-bonded assembly film through ionization in vapor

被引：6

作者：

Yang, Shuguang ^{[1
]}

Li, Yanfang ^{[1
]}

Li, Xiaofeng ^{[1
]}

Li, Yuefang ^{[1
]}

Zhang, Xiaoli ^{[1
]}

Xu, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China

来源：

THIN SOLID FILMS | 2009年 / 517卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Layer-by-layer assembly; Surface patterning; Hydrogen bonding; ULTRATHIN MULTILAYER FILMS; CATIONIC BIPOLAR AMPHIPHILES; POLYELECTROLYTE MULTILAYERS; CHARGED SURFACES; POLYMER-FILMS; THIN-FILMS; CONSECUTIVE ADSORPTION; WEAK POLYELECTROLYTE; FABRICATION; BUILDUP;

D O I：

10.1016/j.tsf.2008.12.001

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The hydrogen-bonded films of poly(vinylpyrrolidone) (PVPON) and poly(acrylic acid) (PAA) were fabricated using layer-by-layer assembly technique. The films were incubated at three different vapor environments (acidic, neutral and basic). PAA would ionize in neutral or basic vapor environment, and then hydrogen bonds linking PVPON and PAA in the film would break and patterned topography would form gradually. Ionization degree of PAA in the film was characterized by Fourier transform infrared spectroscopy. Optical microscope and atomic force microscope were used to observe the film morphologies before and after incubation. Reflective spectroscopy and contact angle measurements were applied to further characterize the patterned surfaces. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：3024 / 3027

页数：4

共 38 条

[1]

Bertrand P, 2000, MACROMOL RAPID COMM, V21, P319, DOI 10.1002/(SICI)1521-3927(20000401)21:7<319::AID-MARC319>3.0.CO

[2]

2-7

[3] Surface-induced structure formation of polymer blends on patterned substrates [J].

Böltau, M ;

Walheim, S ;

Mlynek, J ;

Krausch, G ;

Steiner, U .

NATURE, 1998, 391 (6670) :877-879

[4] Micropatterns of protein and conducting polymer molecules fabricated by layer-by-layer self-assembly and photolithography techniques [J].

Cao, TB ;

Wei, F ;

Jiao, XM ;

Chen, JY ;

Liao, W ;

Zhao, X ;

Cao, WX .

LANGMUIR, 2003, 19 (20) :8127-8129

[5] Self-assembly ultrathin films based on diazoresins [J].

Chen, JY ;

Huang, L ;

Ying, LM ;

Luo, GB ;

Zhao, XS ;

Cao, WX .

LANGMUIR, 1999, 15 (21) :7208-7212

[6] Fabrication of a covalently attached self-assembly multilayer film via H-bonding attraction and subsequent UV-irradiation [J].

Chen, JY ;

Cao, WX .

CHEMICAL COMMUNICATIONS, 1999, (17) :1711-1712

[7] Influence of the degree of ionization on weak polyelectrolyte multilayer assembly [J].

Choi, J ;

Rubner, MF .

MACROMOLECULES, 2005, 38 (01) :116-124

[8] Layer-by-layer assembled multicomposite films [J].

Decher, G ;

Eckle, M ;

Schmitt, J ;

Struth, B .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1998, 3 (01) :32-39

[9] BUILDUP OF ULTRATHIN MULTILAYER FILMS BY A SELF-ASSEMBLY PROCESS .3. CONSECUTIVELY ALTERNATING ADSORPTION OF ANIONIC AND CATIONIC POLYELECTROLYTES ON CHARGED SURFACES [J].

DECHER, G ;

HONG, JD ;

SCHMITT, J .

THIN SOLID FILMS, 1992, 210 (1-2) :831-835

[10] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

← 1 2 3 4 →