The spatial diamond-graphite transition in detonation nanodiamond as revealed by small-angle neutron scattering

被引：33

作者：

Avdeev, Mikhail V. ^{[1
]}

Aksenov, Victor L. ^{[1
,2
]}

Tomchuk, Oleksandr V. ^{[1
,3
]}

Bulavin, Leonid A. ^{[3
]}

Garamus, Vasil M. ^{[4
]}

Osawa, Eiji ^{[5
]}

机构：

[1] Joint Inst Nucl Res, FLNP, Dubna 141980, Russia

[2] IV Kurchatov Atom Energy Inst, Natl Res Ctr, Moscow 123182, Russia

[3] Natl Taras Shevchenko Univ Kyiv, Dept Phys, UA-01601 Kiev, Ukraine

[4] Helmholtz Zentrum Geesthacht, Ctr Mat & Coastal Res, D-21502 Geesthacht, Germany

[5] Shinshu Univ, Asama Res Extens Ctr, NanoCarbon Res Inst, Ueda, Nagano 3868567, Japan

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2013年 / 25卷 / 44期

关键词：

ULTRANANOCRYSTALLINE DIAMOND; POLYDISPERSE; MODEL;

D O I：

10.1088/0953-8984/25/44/445001

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A spatial transition of the carbon state in detonation nanodiamond (DND) from crystalline diamond inside the particle to a graphite-like state at the DND surface is proposed on the basis of small-angle neutron scattering (SANS) analysis. The SANS contrast variation from concentrated (5 wt%) dispersions of DND in liquids (water, dimethylsulfoxide) reveals a shift in the mean scattering length density of DND as compared to pure diamond, which is related to the presence of a non-diamond component in the DND structure. At the same time, the diffusive character of the particle surface is deduced based on the deviation from the Porod law. The two observations are combined to conclude that the continuous radial density profile over the whole particle volume conforms to a simple power law. The profile naturally suggests that non-diamond states are concentrated mainly close to the particle surface; still there is no sharp boundary between the radial distributions of the two states of carbon in DND.

引用

页数：7

共 33 条

[1] The structure of diamond nanoclusters [J].