3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials

被引：335
|
作者：
Li, Shenghua [1 ]
Wang, Yuan [1 ]
Qi, Cai [1 ]
Zhao, Xiuxiu [1 ]
Zhang, Jichuan [1 ]
Zhang, Shaowen [2 ]
Pang, Siping [1 ]
机构：
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 52期
关键词：
energetic materials; heats of detonation; mesoporous materials; metal-organic frameworks; nitrogen-rich heterocycles; HYDROGEN STORAGE; POLYMERS; MECHANISM; SEPARATION; LIGAND;
D O I：
10.1002/anie.201307118
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：14031 / 14035
页数：5
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