3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials

被引:335
|
作者
Li, Shenghua [1 ]
Wang, Yuan [1 ]
Qi, Cai [1 ]
Zhao, Xiuxiu [1 ]
Zhang, Jichuan [1 ]
Zhang, Shaowen [2 ]
Pang, Siping [1 ]
机构
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
关键词
energetic materials; heats of detonation; mesoporous materials; metal-organic frameworks; nitrogen-rich heterocycles; HYDROGEN STORAGE; POLYMERS; MECHANISM; SEPARATION; LIGAND;
D O I
10.1002/anie.201307118
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:14031 / 14035
页数:5
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