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3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials
被引:335
|作者:
Li, Shenghua
[1
]
Wang, Yuan
[1
]
Qi, Cai
[1
]
Zhao, Xiuxiu
[1
]
Zhang, Jichuan
[1
]
Zhang, Shaowen
[2
]
Pang, Siping
[1
]
机构:
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
关键词:
energetic materials;
heats of detonation;
mesoporous materials;
metal-organic frameworks;
nitrogen-rich heterocycles;
HYDROGEN STORAGE;
POLYMERS;
MECHANISM;
SEPARATION;
LIGAND;
D O I:
10.1002/anie.201307118
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:14031 / 14035
页数:5
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