3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials

被引：345

作者：

Li, Shenghua ^{[1
]}

Wang, Yuan ^{[1
]}

Qi, Cai ^{[1
]}

Zhao, Xiuxiu ^{[1
]}

Zhang, Jichuan ^{[1
]}

Zhang, Shaowen ^{[2
]}

Pang, Siping ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China

[2] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 52期

关键词：

energetic materials; heats of detonation; mesoporous materials; metal-organic frameworks; nitrogen-rich heterocycles; HYDROGEN STORAGE; POLYMERS; MECHANISM; SEPARATION; LIGAND;

D O I：

10.1002/anie.201307118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：14031 / 14035

页数：5

共 56 条

[1]

Agrawal J.P., 2010, High Energy Materials

[2]

[Anonymous], EXPLOSIVE

[3] On the detonation parameters of octanitrocubane [J].

Astakhov, AM ;

Stepanov, RS ;

Babushkin, AY .

COMBUSTION EXPLOSION AND SHOCK WAVES, 1998, 34 (01) :85-87

[4]

Bae Y.-S., 2011, Angew. Chem, V123, P11790

[5] Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture [J].

Bae, Youn-Sang ;

Snurr, Randall Q. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (49) :11586-11596

[6] On the mechanism of hydrogen storage in a metal-organic framework material [J].

Belof, Jonathan L. ;

Stern, Abraham C. ;

Eddaoudi, Mohamed ;

Space, Brian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15202-15210

[7] Structural studies of molecular-based nanoporous materials. Novel networks of silver(I) cations assembled with the polydentate N-donor bases hexamethylenetetramine and 1,3,5-triazine [J].

Bertelli, M ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM ;

Sironi, A .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (07) :1271-1276

[8] Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].

Bloch, Eric D. ;

Queen, Wendy L. ;

Krishna, Rajamani ;

Zadrozny, Joseph M. ;

Brown, Craig M. ;

Long, Jeffrey R. .

SCIENCE, 2012, 335 (6076) :1606-1610

[9] Post-synthetic Structural Processing in a Metal-Organic Framework Material as a Mechanism for Exceptional CO2/N2 Selectivity [J].

Bloch, Witold M. ;

Babarao, Ravichandar ;

Hill, Matthew R. ;

Doonan, Christian J. ;

Sumby, Christopher J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10441-10448

[10] Metal-Organic Frameworks (MOFs) as Safer, Structurally Reinforced Energetics [J].

Bushuyev, Oleksandr S. ;

Peterson, Geneva R. ;

Brown, Preston ;

Maiti, Amitesh ;

Gee, Richard H. ;

Weeks, Brandon L. ;

Hope-Weeks, Louisa J. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (05) :1706-1711

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