Citric acid/ZrO2 nanocomposite inducing thermal barrier and self-cleaning properties on protein fibers

被引:46
作者
Gashti, Mazeyar Parvinzadeh [1 ]
Almasian, Arash [2 ]
机构
[1] Islamic Azad Univ, Shahre Rey Branch, Dept Text, Tehran, Iran
[2] Inst Color Sci & Technol, Dept Environm Res, Tehran, Iran
关键词
Fabrics/textiles; Thermal properties; Chemical analysis; NANO-TITANIUM-DIOXIDE; PHOTOCATALYTIC DEGRADATION; ORGANIC-COMPOUNDS; CELLULOSE FIBER; WOOL; ACID; ZIRCONIA; TIO2; TEXTILES; ADSORPTION;
D O I
10.1016/j.compositesb.2013.04.037
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present research carried out to stabilize nano-ZrO2 on the wool fabric using citric acid (CA) as a cross-linking agent and sodium hypophosphite (SHP) as a catalyst under UV irradiation. The influence of the amount of nano-ZrO2 on the performance of wool fiber was investigated by the use of Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), energy dispersive X-ray spectroscope (EDX) and reflectance spectrophotometer (RS). The possible interactions between nano-ZrO2 particles, cross-linking agent and wool free radicals were elucidated by the FTIR spectroscopy. Results indicated that the stabilized nano-ZrO2 enhances the thermal stability of wool. Photo-catalytic activities of the coated wool were evaluated through degradation of methylene blue (MB) under UV irradiation. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:340 / 349
页数:10
相关论文
共 71 条
[1]   Functional cellulose fibers via polycarboxylic acid/carbon nanotube composite coating [J].
Alimohammadi, Farbod ;
Gashti, Mazeyar Parvinzadeh ;
Shamei, Ali .
JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2013, 10 (01) :123-132
[2]   A novel method for coating of carbon nanotube on cellulose fiber using 1,2,3,4-butanetetracarboxylic acid as a cross-linking agent [J].
Alimohammadi, Farbod ;
Gashti, Mazeyar Parvinzadeh ;
Shamei, Ali .
PROGRESS IN ORGANIC COATINGS, 2012, 74 (03) :470-478
[3]   2,4-dichlorophenoxyacetic acid (2,4-D) photodegradation using an Mn+/ZrO2, photocatalyst:: XPS, UV-vis, XRD characterization [J].
Alvarez, M. ;
Lopez, T. ;
Odriozola, J. A. ;
Centeno, M. A. ;
Dominguez, M. T. ;
Montes, M. ;
Quintana, P. ;
Aguilar, D. H. ;
Gonzalez, R. D. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 73 (1-2) :34-41
[4]   The adsorption and activation of CO molecules on ZrO2 catalysts having low-coordinated surface sites [J].
Anpo, M ;
Moon, SC .
RESEARCH ON CHEMICAL INTERMEDIATES, 1999, 25 (01) :1-12
[5]   EFFECTS OF CITRATE ADSORPTION ON THE INTERACTIONS BETWEEN ZIRCONIA SURFACES [J].
BIGGS, S ;
SCALES, PJ ;
LEONG, YK ;
HEALY, TW .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (17) :2921-2928
[6]  
Bingshe X., 2007, J PHOTOCH PHOTOBIO A, V188, P98, DOI DOI 10.1016/J.JPHOTOCHEM.2006.11.025
[7]   Self-cleaning of wool-polyamide and polyester textiles by TiO2-rutile modification under daylight irradiation at ambient temperature [J].
Bozzi, A ;
Yuranova, T ;
Kiwi, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 172 (01) :27-34
[8]   Structural characterization of wool by thermal mechanical analysis of yarns [J].
Cao, JN ;
Bhoyro, AY .
TEXTILE RESEARCH JOURNAL, 2001, 71 (01) :63-66
[9]   Crosslinking of cotton cellulose with succinic acid in the presence of titanium dioxide nano-catalyst under UV irradiation [J].
Chen, Cheng-Chi ;
Wang, Chyung-Chyung .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2006, 40 (01) :31-38
[10]   Fabricating Superhydrophilic Wool Fabrics [J].
Chen, Dong ;
Tan, Longfei ;
Liu, Huiyu ;
Hu, Junyan ;
Li, Yi ;
Tang, Fangqiong .
LANGMUIR, 2010, 26 (07) :4675-4679