CRYSTALLOGRAPHIC ANALYSIS OF SULFIDES RELATED TO BISMUTHINITE Bi2S3

被引：3

作者：

Borisov, S. V. ^{[1
]}

Magarill, S. A. ^{[1
]}

Pervukhina, N. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 04期

关键词：

crystallographic analysis; sulfides; pseudotetragonal cation framework; pseudohexagonal anion framework; bismuthinite Bi2S3-aikinite CuPbBiS3 family; cation and anion sublattices; symmetry-composition relationship; SOLID-SOLUTION SERIES; CRYSTAL-STRUCTURE; PB;

D O I：

10.1134/S0022476616040119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystallographic analysis of Bi2S3, CuPbBi5S9, CuPbBi3S6, and CuPbBiS3 compounds, representing a series with a successive replacement of a part of Bi atoms by Pb+Cu, shows that they are characterized by a stable combination of a pseudotetragonal cation framework with a pseudohexagonal anion one, which is common for all structures, within orthorhombic unit cells with n sizes of 11.2 angstrom, 4 angstrom, and 11.5 angstrom. The Bi2S3 cation framework is retained for the heavy Bi+Pb, and additional light Cu fill the available vacant sites without changing its geometry but varying the crystallographic symmetry within the orthorhombic crystal symmetry and unit cells of n standard blocks (11.2x4x11.5 angstrom(3)).

引用

页码：704 / 709

页数：6

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