Conformational and coordination plasticity in silver(I) cryptates

被引：35
|
作者：
McKee, V [1 ]
Nelson, J
Speed, DJ
Town, RM
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
[2] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
[3] Open Univ, Milton Keynes MK7 6AA, Bucks, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 24期
关键词：
D O I：
10.1039/b104434f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of a disilver aminocryptate with silver accommodated in the faces rather than within the tetramine-derived caps of the crypt shows close contact between Ag+ cations indicative of interaction between the d(10) cations. On standing in solution, a second, trisilver, cryptate is isolated, where close contact between the silver cations, now triangularly disposed, is still present. A pseudoreversible wave close to 0 V vs. Ag/AgCl is tentatively assigned to the one-electron I,I <-> I,O redox process in the disilver cryptate.
引用
收藏
页码：3641 / 3646
页数：6
相关论文
共 50 条
  • [1] SYNTHESES, SPECTROSCOPY AND CRYSTAL-STRUCTURE OF SEVERAL BINUCLEAR SILVER(I) CRYPTATES
    YU, SY
    LUO, QH
    SHEN, MC
    HUANG, XY
    YANG, WH
    ZHANG, Z
    INORGANICA CHIMICA ACTA, 1994, 223 (1-2) : 181 - 186
  • [2] Polymeric silver(I) coordination tubes
    Pickering, AL
    Seeber, G
    Long, DL
    Cronin, L
    CHEMICAL COMMUNICATIONS, 2004, (02) : 136 - 137
  • [3] Review: Multimetallic silver(I)-pyridinyl complexes: coordination of silver(I) and luminescence
    Njogu, Eric M.
    Omondi, Bernard
    Nyamori, Vincent O.
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (19) : 3389 - 3431
  • [4] Equilibrium unfolding and conformational plasticity of troponin I and T
    Martins, SM
    Chapeaurouge, A
    Ferreira, ST
    EUROPEAN JOURNAL OF BIOCHEMISTRY, 2002, 269 (22): : 5484 - 5491
  • [5] Conformational plasticity of the type I maltose ABC importer
    Boehm, Simon
    Licht, Anke
    Wuttge, Steven
    Schneider, Erwin
    Bordignon, Enrica
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (14) : 5492 - 5497
  • [6] Resolvation of Reaction Sites of Extracting Agents upon Formation of Silver(I) Cryptates in Aqueous Acetonitrile
    Afanas'ev, V. N.
    Grechin, A. G.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (08) : 1281 - 1288
  • [7] CONFORMATIONAL PREFERENCE AND STRUCTURAL SIMILARITY OF THE LANTHANIDE [2.2.1] CRYPTATES
    GANSOW, OA
    PRUETT, DJ
    TRIPLETT, KB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (15) : 4408 - 4409
  • [8] FROM 3-COORDINATION TO 4-COORDINATION IN COPPER(I) AND SILVER(I)
    BURDETT, JK
    EISENSTEIN, O
    INORGANIC CHEMISTRY, 1992, 31 (10) : 1758 - 1762
  • [9] A study on oxygen insertion in dinuclear silver cryptates
    Wang, ZL
    Luo, QH
    Duan, CY
    Shen, CY
    Li, YZ
    DALTON TRANSACTIONS, 2004, (07) : 1104 - 1111
  • [10] A silver(I) coordination polymer luminescent thermometer
    He, Yuan-Chun
    Xu, Na
    Zheng, Xiaofeng
    Yu, Yang
    Ling, Baoping
    You, Jinmao
    DYES AND PIGMENTS, 2017, 136 : 577 - 582
12345