Extraction from striped weakfish (Cynoscion striatus) wastes with pressurized CO2: Global yield, composition, kinetics and cost estimation

被引:17
作者
Aguiar, Ana Carolina [1 ]
Visentainer, Jesui V. [2 ]
Martinez, Julian [1 ]
机构
[1] Univ Estadual Campinas, Coll Food Engn, DEA, UNICAMP,FEA, BR-13083862 Campinas, SP, Brazil
[2] Univ Estadual Maringa, Dept Chem, BR-87020900 Maringa, PR, Brazil
关键词
Striped weakfish; Supercritical extraction; Fatty acids; Modeling; Cost estimation; SUPERCRITICAL-FLUID EXTRACTION; MACKEREL SCOMBER-SCOMBRUS; VEGETABLE-OIL EXTRACTION; FATTY-ACIDS; MASS-TRANSFER; PHASE-EQUILIBRIUM; LIPID EXTRACTION; ETHYL-ESTERS; SOLUBILITIES; OLEORESIN;
D O I
10.1016/j.supflu.2012.07.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Extraction with pressurized carbon dioxide was applied to recover polyunsaturated fatty acids (PUFA) from striped weakfish (Cynoscion striatus) wastes. Extraction yield was evaluated at temperatures from 30 to 60 degrees C and pressures from 20 to 30 MPa. Temperature and pressure of 30 degrees C and 20 MPa were selected to evaluate process kinetics. A scale-up was performed by keeping the ratio constant between solid mass and solvent flow rate. Mathematical models were applied to the extraction curves, and the broken and intact cell model provided good fits, being applied to multiple curves simultaneously. Manufacturing cost of the extraction was estimated, and an optimal extraction time was observed by the end of the convective period. Finally, the extracts were analyzed by gas chromatography, and over 20% of the oil was composed by PUFA, whose concentration increased with extraction time. Therefore, this work shows that pressurized CO2 extraction can obtain valuable compounds from fish residues. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 10
页数:10
相关论文
共 60 条
[1]  
[Anonymous], COMP PAUL FORC LUZ
[2]  
[Anonymous], 1995, OFFICIAL METHODS ANA, V1
[3]  
[Anonymous], ASHRAE REFR HDB
[4]  
[Anonymous], OPERACOES CORN SISTE
[5]  
[Anonymous], C P LIP FAT OIL OPP
[6]  
[Anonymous], 2004, SUPERCRITICAL FLUID
[7]  
[Anonymous], DISCARDS WORLDS MARI
[8]   Modeling the supercritical fluid extraction of hazelnut and walnut oils [J].
Bernardo-Gil, M. Gabriela ;
Casquilho, Miguel .
AICHE JOURNAL, 2007, 53 (11) :2980-2985
[9]  
BLIGH EG, 1959, CAN J BIOCHEM PHYS, V37, P911
[10]  
Brunner G., 1994, Gas extraction: an introduction to fundamentals of supercritical fluids and the application to separation processes