Pyrolysis of Waste Plastics: Effect of Heating Rate on Product Yields and Oil Properties

被引:3
作者
Tao Pei [1 ]
Ma Xiao-bo [1 ]
Chen De-zhen [1 ]
Wang Hai [1 ]
机构
[1] Tongji Univ, Sch Mech Engn, Shanghai 200092, Peoples R China
来源
ENVIRONMENT-ENHANCING ENERGY AND BIOCHEMICALS CONFERENCE II | 2013年 / 666卷
关键词
waste plastics; heating rate; pyrolysis; product yields; oil properties; POLYETHYLENE; REACTOR; TEMPERATURE; MIXTURES;
D O I
10.4028/www.scientific.net/AMR.666.1
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Selecting typical waste plastics, polyethylene (PE), polypropylene (PP) and polyvinyl chloride (PVC), and their mixture PE/PP/PVC as experimental samples, pyrolysis experiments were conducted on tubular furnace reactor at heating rates of 3.7 degrees C.min(-1), 9.0 degrees C.min(-1), 20.6 degrees C.min(-1) and 33.3 degrees C.min(-1) respectively to investigate effect of heating rate on yields of pyrolysis product (cracking oil, cracking gas and residue) and oil properties. The results showed that cracking oil yield was increased, but both the yields of cracking gas and residue were decreased, together with increasing heating rate. The decrease of residue yield was negligible. With the rise of heating rate, calorific value of cracking oil produced from PE and mixture of plastic was decreased and calorific value of oil produced from PP was increased, while that of PVC was decreased at first and increased later. Variations in components distribution of cracking oil generated from different kinds of plastics were different from each other. The results are probably supposed to provide reference for the optimization of pyrolysis process parameters of waste plastics.
引用
收藏
页码:1 / 10
页数:10
相关论文
共 24 条
[11]   Fuels by pyrolysis of waste plastics from agricultural and packaging sectors in a pilot scale reactor [J].
Miskolczi, N. ;
Angyal, A. ;
Bartha, L. ;
Valkai, I. .
FUEL PROCESSING TECHNOLOGY, 2009, 90 (7-8) :1032-1040
[12]   Composition of products from the pyrolysis of polyethylene and polystyrene in a closed batch reactor: Effects of temperature and residence time [J].
Onwudili, Jude A. ;
Insura, Nagi ;
Williams, Paul T. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 86 (02) :293-303
[13]  
Ren Dongmei, 2005, QILU PETROCHEMICAL T, V3, P173
[14]   Pyrolysis of pine (Pinus Brutia Ten.) chips:: 1.: Effect of pyrolysis temperature and heating rate on the product yields [J].
Sensöz, S ;
Can, M .
ENERGY SOURCES, 2002, 24 (04) :347-355
[15]   Conversion of low density polyethylene into petrochemical feedstocks using a continuous screw kiln reactor [J].
Serrano, DP ;
Aguado, J ;
Escola, JM ;
Garagorri, E .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2001, 58 :789-801
[16]  
Shi Baoying, 2006, HANGZHOU CHEM IND, V4, P35
[17]  
Shi Baoying, 2008, SCI TECHNOLOGY CHEM, V2, P29
[18]  
Shi Yaohua, 2011, ENERGY CONSERVATION, V3, P199
[19]   Study of the pyrolysis of municipal solid waste for the production of valuable products [J].
Velghe, I. ;
Carleer, R. ;
Yperman, J. ;
Schreurs, S. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2011, 92 (02) :366-375
[20]  
Williams EA, 1997, J CHEM TECHNOL BIOT, V70, P9