Diversity-Oriented Approach to Macrocyclic Cyclophane Derivatives via Ring-Closing Metathesis

被引：15
作者：
Kotha, Sambasivarao [1 ]
Shirbhate, Mukesh E. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India
来源：
SYNLETT | 2012年 / 15期
关键词：
paracyclophane; macrocycles; ring-closing metathesis; oxidation; alkylation; OLEFIN-METATHESIS; CATALYTIC CYCLOPHANES; CLAISEN REARRANGEMENT; STRATEGIC UTILIZATION; SYNTHETIC APPROACH; NATURAL-PRODUCTS; MOLECULES; LONGITHORONES; AROMATICS; HYDROGEN;
D O I：
10.1055/s-0032-1317020
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A short synthetic approach to the macrocyclic framework of longithorone C is described via ring-closing metathesis using the Grubbs 2nd generation catalyst.
引用
收藏
页码：2183 / 2188
页数：6
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共 79 条
[61]   Ruthenium-catalyzed ROM, RCM and CM of enyne [J].
Mori, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 213 (01) :73-79
[62]   Efficient synthesis of 19-31 membered macrocyclic tetralactones via ring closing metathesis in ionic liquids [J].
Muthusamy, Sengodagounder ;
Azhagan, Datschnamoorthy .
TETRAHEDRON, 2010, 66 (41) :8196-8202
[63]   The influence of natural products upon drug discovery [J].
Newman, DJ ;
Cragg, GM ;
Snader, KM .
NATURAL PRODUCT REPORTS, 2000, 17 (03) :215-234
[64]   Metathesis reactions in total synthesis [J].
Nicolaou, KC ;
Bulger, PG ;
Sarlah, D .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (29) :4490-4527
[65]   INTRAMOLECULAR TYPE-II METALLO-ENE REACTIONS OF (2-ALKENYLALLYL)MAGNESIUM CHLORIDES - REGIOCHEMICAL AND STEREOCHEMICAL STUDIES [J].
OPPOLZER, W ;
PITTELOUD, R ;
STRAUSS, HF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6476-6477
[66]   Synthesis and study of anti-inflammatory activity of some novel cyclophane amides [J].
Rajakumar, Perumal ;
Rasheed, A. Mohammed Abdul ;
Rabia, A. Iman ;
Chamundeeswari, D. .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2006, 16 (23) :6019-6023
[67]   Synthesis, characterization, and anti-bacterial efficacy of some novel cyclophane amide [J].
Rajakumar, Perumal ;
Rasheed, A. Mohammed Abdul ;
Balu, P. M. ;
Murugesan, K. .
BIOORGANIC & MEDICINAL CHEMISTRY, 2006, 14 (22) :7458-7467
[68]   Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo-[3.2.1]-octanes [J].
Saint-Dizier, AC ;
Kilburn, JD .
TETRAHEDRON LETTERS, 2002, 43 (35) :6201-6203
[69]   COPPER(I) CATALYSIS OF OLEFIN PHOTOREACTIONS .9. PHOTOBICYCLIZATION OF ALPHA-ALKENYLALLYL, BETA-ALKENYLALLYL, AND GAMMA-ALKENYLALLYL ALCOHOLS [J].
SALOMON, RG ;
COUGHLIN, DJ ;
GHOSH, S ;
ZAGORSKI, MG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (04) :998-1007
[70]   Multiple metal-carbon bonds for catalytic metathesis reactions (Nobel lecture) [J].
Schrock, Richard R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3748-3759
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