5,10,15,20-Tetra-p-phenylsulfonyporphinatocobalt(III), a water-soluble Co(III) porphyrin

被引：4

作者：

Mathura, Sadhna ^{[1
]}

de Sousa, Alvaro S. ^{[1
]}

Fernandes, Manuel A. ^{[1
]}

Marques, Helder M. ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, Inst Mol Sci, ZA-2050 Johannesburg, South Africa

来源：

INORGANICA CHIMICA ACTA | 2012年 / 392卷

基金：

新加坡国家研究基金会;

关键词：

Cobalt porphyrins; Co(TPPS)(H2O)(2)](-); SQUEEZE algorithm; MOLECULAR-MECHANICS; AQUEOUS-SOLUTION; CRYSTAL; REDUCTION; KINETICS; METAL; SUBSTITUTION; EQUILIBRIUM; PERCHLORATE; IMIDAZOLE;

D O I：

10.1016/j.ica.2012.05.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An alternative procedure is described for producing diffraction-quality crystals of the sodium salt of the water-soluble porphyrin diaqua-5,10,15,20-tetra-p-phenylsulfonyporphinatocobalt(III), Na[Co(TPPS)(H2O)(2)]center dot 4H(2)O by vapour diffusion of ethyl acetate into an aqueous solution of the porphyrin overlaid with a layer of acetone. The structure contains a large amount of disordered solvent in channels but application of an appropriate algorithm (SQUEEZE - an algorithm incorporated into PLATON that applies a Fourier transform of the observed density in the solvent areas and incorporates its contribution to the structure factors) permits a structure solution. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：108 / 111

页数：4