The first organoelement oxides containing three different metals;: synthesis and structure of (Ph2SiOR2SnOMO) [R = (CH2)3NMe2; M = Bu2tSn, Bu2tGe, PhB]

被引：15
|
作者：
Beckmann, J [1 ]
Jurkschat, K [1 ]
Pieper, N [1 ]
Schürmann, M [1 ]
机构：
[1] Univ Dortmund, Fachbereich Chem, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 12期
关键词：
D O I：
10.1039/a902428j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Umpolung of ring strain by intramolecular Sn-N Lewis acid-Lewis base interaction is the key for the synthesis of the first organoelement oxides of the type (Ph2SiOR2SnOMO) [R = (CH2)(3)NMe2; M = (Bu2Sn)-Sn-t, (Bu2Ge)-Ge-t, PhB] which hold potential as precursors to tertiary metal oxides.
引用
收藏
页码：1095 / 1096
页数：2
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