Specific Heat Capacity at Constant Pressure of Ethanol by Flow Calorimetry

被引:18
作者
Miyazawa, Taishi [1 ]
Kondo, Satoshi [1 ]
Suzuki, Takuya [2 ]
Sato, Haruki [3 ]
机构
[1] Keio Univ, Grad Sch Sci & Technol, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
[2] Keio Univ, Former Grad Sch Sci & Technol, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
[3] Keio Univ, Dept Syst Design Engn, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
关键词
LIQUID; HCFC-123; METHYL; ETHYL;
D O I
10.1021/je2013473
中图分类号
O414.1 [热力学];
学科分类号
摘要
Specific heat capacities at a constant pressure of liquid ethanol in a temperature range from (265 to 348) K at a pressure of 500 kPa were measured by using flow calorimetry. The expanded uncertainty evaluated is from (0.55 to 0.89) % including the repeatability. Existing measurements by other researchers and derived specific heat capacity values from the existing equation of state provide greater values beyond the uncertainty. To confirm the reliability of our measurements, we measured the heat capacities under the same conditions for different liquid ethanol samples provided from different manufacturers. The measurements almost perfectly agree each other. The measurements obtained for two different samples of liquid ethanol are reported.
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页码:1700 / 1707
页数:8
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