A study of micropores in single-walled carbon nanotubes by the adsorption of gases and vapors

被引:136
作者
Eswaramoorthy, M [1 ]
Sen, R [1 ]
Rao, CNR [1 ]
机构
[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
关键词
D O I
10.1016/S0009-2614(99)00311-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Adsorption of N-2, benzene and methanol have been studied on as-prepared single-walled carbon nanotubes (SWNT) as well as SWNTs treated with HCl and HNO3. These nanotubes are good microporous materials with total surface areas well above 400 m(2)/g and internal surface areas of 300 m(2)/g or higher. Benzene molecules are shown to be adsorbed within the pores of the SWNTs. (C) 1999 Elsevier Science B.V, All rights reserved.
引用
收藏
页码:207 / 210
页数:4
相关论文
共 13 条
[1]  
Dujardin E, 1998, ADV MATER, V10, P611, DOI 10.1002/(SICI)1521-4095(199805)10:8<611::AID-ADMA611>3.0.CO
[2]  
2-8
[3]  
Engelhardt H., 2008, HDB HETEROGENOUS CAT, P427
[4]   METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].
HORVATH, G ;
KAWAZOE, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475
[5]   Capillary condensation of N2 on multiwall carbon nanotubes [J].
Inoue, S ;
Ichikuni, N ;
Suzuki, T ;
Uematsu, T ;
Kaneko, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (24) :4689-4692
[6]   Large-scale production of single-walled carbon nanotubes by the electric-arc technique [J].
Journet, C ;
Maser, WK ;
Bernier, P ;
Loiseau, A ;
delaChapelle, ML ;
Lefrant, S ;
Deniard, P ;
Lee, R ;
Fischer, JE .
NATURE, 1997, 388 (6644) :756-758
[7]   Functionalised carbon nanotubes from solutions [J].
Rao, CNR ;
Govindaraj, A ;
Satishkumar, BC .
CHEMICAL COMMUNICATIONS, 1996, (13) :1525-1526
[8]   Synthesis of multi-walled and single-walled nanotubes, aligned-nanotube bundles and nanorods by employing organometallic precursors [J].
Rao, CNR ;
Govindaraj, A ;
Sen, R ;
Satishkumar, BC .
MATERIALS RESEARCH INNOVATIONS, 1998, 2 (03) :128-141
[9]   Characterization of large-pore MCM-41 molecular sieves obtained via hydrothermal restructuring [J].
Sayari, A ;
Liu, P ;
Kruk, M ;
Jaroniec, M .
CHEMISTRY OF MATERIALS, 1997, 9 (11) :2499-2506
[10]   THE USE OF GAS-ADSORPTION FOR THE CHARACTERIZATION OF POROUS SOLIDS [J].
SING, KSW .
COLLOIDS AND SURFACES, 1989, 38 (1-3) :113-124