Self-Healing Polymers Based on Reversible Covalent Bonds

被引:64
作者
Kuhl, Natascha
Bode, Stefan
Hager, Martin D. [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ]
机构
[1] Friedrich Schiller Univ Jena, Lab Organ & Macromol Chem IOMC, Humboldtstr 10, D-07743 Jena, Germany
[2] Friedrich Schiller Univ Jena, Jena Ctr Soft Mater JCSM, Philosophenweg 7, D-07743 Jena, Germany
来源
SELF-HEALING MATERIALS | 2016年 / 273卷
关键词
Diels-Alder reaction; Disulfide bonds; Intrinsic self-healing polymers; Radicals; Reversible addition reactions; Reversible covalent bonds; Self-healing polymers; DIELS-ALDER REACTION; CROSS-LINKED POLYMER; ROOM-TEMPERATURE; DYNAMIC POLYMERS; SUPRAMOLECULAR POLYMERS; ADAPTABLE NETWORKS; RADICAL POLYMERIZATION; FURAN POLYMERS; CHEMISTRY; EPOXY;
D O I
10.1007/12_2015_336
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Starting with reversible polymer networks based on the Diels-Alder reaction of furan and maleimide, a large variety of different self-healing polymers based on reversible covalent interactions have been developed in the last decade. These intrinsic self-healing polymers are mainly based on reversible addition reactions, exchange reactions, and condensations. The most prominent examples of such materials are based on Diels-Alder chemistry, photocycloadditions, disulfide reactions, acylhydrazones, and reversible radical reactions.
引用
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页码:1 / 58
页数:58
相关论文
共 146 条
[1]   Healable dual organic-inorganic crosslinked sol-gel based polymers: Crosslinking density and tetrasulfide content effect [J].
AbdolahZadeh, Mina ;
Esteves, A. Catarina C. ;
van der Zwaag, Sybrand ;
Garcia, Santiago J. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2014, 52 (14) :1953-1961
[2]   Self-Healing of Covalently Cross-Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under Visible Light [J].
Amamoto, Yoshifumi ;
Otsuka, Hideyuki ;
Takahara, Atsushi ;
Matyjaszewski, Krzysztof .
ADVANCED MATERIALS, 2012, 24 (29) :3975-3980
[3]  
[Anonymous], 2012, INT J MODERN BIOL ME
[4]   Synthesis and characterization of reversible and self-healable networks based on acylhydrazone groups [J].
Apostolides, Demetris E. ;
Patrickios, Costas S. ;
Leontidis, Epameinondas ;
Kushnir, Michelle ;
Wesdemiotis, Chrys .
POLYMER INTERNATIONAL, 2014, 63 (09) :1558-1565
[5]   Investigation of the thermal self-healing mechanism in a cross-linked epoxy system [J].
Bai, Nan ;
Simon, George P. ;
Saito, Kei .
RSC ADVANCES, 2013, 3 (43) :20699-20707
[6]   Synthesis of a diamine cross-linker containing Diels-Alder adducts to produce self-healing thermosetting epoxy polymer from a widely used epoxy monomer [J].
Bai, Nan ;
Saito, Kei ;
Simon, George P. .
POLYMER CHEMISTRY, 2013, 4 (03) :724-730
[7]   Redox-Responsive Dynamic-Covalent Assemblies: Stars and Miktoarm Stars [J].
Bapat, Abhijeet P. ;
Ray, Jacob G. ;
Savin, Daniel A. ;
Sumerlin, Brent S. .
MACROMOLECULES, 2013, 46 (06) :2188-2198
[8]   Self-Healing Materials via Reversible Crosslinking of Poly(ethylene oxide)-Block-Poly(furfuryl glycidyl ether) (PEO-b-PFGE) Block Copolymer Films [J].
Barthel, Markus J. ;
Rudolph, Tobias ;
Teichler, Anke ;
Paulus, Renzo M. ;
Vitz, Juergen ;
Hoeppener, Stephanie ;
Hager, Martin D. ;
Schacher, Felix H. ;
Schubert, Ulrich S. .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (39) :4921-4932
[9]   Chemistry of Crosslinking Processes for Self-Healing Polymers [J].
Billiet, Stijn ;
Hillewaere, Xander K. D. ;
Teixeira, Roberto F. A. ;
Du Prez, Filip E. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (04) :290-309
[10]   Self-healing metallopolymers based on cadmium bis(terpyridine) complex containing polymer networks [J].
Bode, S. ;
Bose, R. K. ;
Matthes, S. ;
Ehrhardt, M. ;
Seifert, A. ;
Schacher, F. H. ;
Paulus, R. M. ;
Stumpf, S. ;
Sandmann, B. ;
Vitz, J. ;
Winter, A. ;
Hoeppener, S. ;
Garcia, S. J. ;
Spange, S. ;
van der Zwaag, S. ;
Hager, M. D. ;
Schubert, U. S. .
POLYMER CHEMISTRY, 2013, 4 (18) :4966-4973