An amphiphilic conjugated polymer as an aggregation-based multifunctional sensing platform with multicolor fluorescence response

被引：23

作者：

Bao, Yinyin ^{[2
]}

Wang, Taisheng ^{[1
]}

Li, Qianbiao ^{[1
]}

Du, Fanfan ^{[1
]}

Bai, Ruke ^{[1
]}

Smet, Mario ^{[2
]}

Dehaen, Wim ^{[2
]}

机构：

[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China

[2] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium

来源：

POLYMER CHEMISTRY | 2014年 / 5卷 / 03期

关键词：

METAL ION-RECOGNITION; OPTICAL-DETECTION; INTERPOLYELECTROLYTE COMPLEXES; MERCURY IONS; POLYELECTROLYTES; DNA; CHEMOSENSOR; SENSORS; DESIGN; HG2+;

D O I：

10.1039/c3py01014g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We designed and synthesized an amphiphilic conjugated polymer P1 based on the 2,2'-biimidazole unit, and then investigated its sensing properties as an aggregation-based platform. P1 shows multicolor emission in organic solvents at different water contents, and is demonstrated to be the first multicolor fluorescent sensor for water. And it exhibits visually noticeable multicolor fluorescence response to Ag+ in aqueous dioxane and to Hg2+ ions in aqueous ethanol. In addition, the polymer-Hg2+ complex system can be used as an efficient cysteine fluorescent sensor based on the aggregation disaggregation strategy. These results validate P1 as an efficient multifunctional platform with multicolor fluorescence response.

引用

页码：792 / 798

页数：7

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