High-performance SERS substrates: Advances and challenges

被引：278

作者：

Sharma, Bhavya ^{[1
]}

Cardinal, M. Fernanda ^{[1
]}

Kleinman, Samuel L. ^{[1
]}

Greeneltch, Nathan G. ^{[1
]}

Frontiera, Renee R. ^{[2
]}

Blaber, Martin G. ^{[1
]}

Schatz, George C. ^{[1
]}

Van Duyne, Richard P. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

MRS BULLETIN | 2013年 / 38卷 / 08期

基金：

美国国家科学基金会;

关键词：

SURFACE-ENHANCED RAMAN; GOLD NANOPARTICLE DIMERS; EXCITATION SPECTROSCOPY; PLASMON RESONANCE; SEEDED GROWTH; HOT-SPOTS; METAL NANOPARTICLES; SILVER NANOCUBES; SCATTERING; ASSEMBLIES;

D O I：

10.1557/mrs.2013.161

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Surface-enhanced Raman spectroscopy (SERS) is highly dependent upon the substrate, where excitation of the localized metal surface plasmon resonance enhances the vibrational scattering signal of proximate analyte molecules. This article reviews recent progress in the fabrication of SERS substrates and the requirements for characterization of plasmonic materials as SERS platforms. We discuss bottom-up fabrication of SERS substrates and illustrate the advantages of rational control of metallic nanoparticle synthesis and assembly for hot spot creation. We also detail top-down methods, including nanosphere lithography for the preparation of tunable, highly sensitive, and robust substrates, as well as the unique benefits of tip-enhanced Raman spectroscopy for simultaneous acquisition of molecular vibrational information and high spatial resolution imaging. Finally, we discuss future prospects and challenges in SERS, including the development of surface-enhanced femtosecond stimulated Raman spectroscopy, microfluidics with SERS, creating highly reproducible substrates, and the need for reliable characterization of substrates.

引用

页码：615 / 624

页数：10

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