Metal carbonyl complexes containing heterocyclic nitrogen ligands -: Part IX.: MnBr(CO)3(3,3′-R-2,2′-biquinoline) compounds

被引：10

作者：

Moya, SA

Guerrero, J

Pastene, R

Azócar-Guzmán, I

Pardey, AJ

机构：

[1] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Mat, Santiago, Chile

[2] Cent Univ Venezuela, Fac Ciencia, Escuela Quim, Caracas 1020A, Venezuela

来源：

POLYHEDRON | 2002年 / 21卷 / 04期

关键词：

metallic carbonyl complexes; manganese; heterocyclic nitrogen ligands;

D O I：

10.1016/S0277-5387(01)01009-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fac-MnBr(CO)(3)(3,3'-R-2,2'-biquinoline) (R = CH3 and CH3; H and H; -CH2-CH2- or -CH2-CH2-CH2-) compounds were synthesized and characterized. The fac-conformation for the carbonyl complexes was established by IR spectroscopy. Conformational effects were investigated by means of H-1 NMR and UV-Vis spectroscopical and electrochemical properties and these properties were compared with related rhenium compounds. (C) 2002 Published by Elsevier Science Ltd.

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页码：439 / 444

页数：6

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