Highly emissive, nine-coordinate enantiopure lanthanide complexes incorporating tetraazatriphenylenes as probes for DNA

被引:65
作者
Bobba, G [1 ]
Frias, JC [1 ]
Parker, D [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
D O I
10.1039/b201451n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of q = 0 Delta- and Lambda-Tb and Eu complexes with poly(dAdT), poly(dGdC) and calf-thymus DNA has been examined by absorption, emission and chiroptical spectroscopy and is sensitive to complex helicity, base-pair type and the nature of the lanthanide excited state.
引用
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页码:890 / 891
页数:2
相关论文
共 19 条
[1]   Luminescent materials and devices: lanthanide azatriphenylene complexes and electroluminescent charge transfer systems [J].
Bakker, BH ;
Goes, M ;
Hoebe, N ;
van Ramesdonk, HJ ;
Verhoeven, JW ;
Werts, MHV ;
Hofstraat, JW .
COORDINATION CHEMISTRY REVIEWS, 2000, 208 :3-16
[2]  
BLOOMFIELD VA, 1974, PHYSICAL CHEM NUCL A
[3]   Chiroptical, ESMS and NMR spectroscopic study of the interaction of enantiopure lanthanide complexes with selected self-complementary dodecamer oligonucleotides [J].
Bobba, G ;
Dickins, RS ;
Kean, SD ;
Mathieu, CE ;
Parker, D ;
Peacock, RD ;
Siligardi, G ;
Smith, MJ ;
Williams, JAG ;
Geraldes, CFGC .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, Royal Society of Chemistry (09) :1729-1737
[4]   DNA binding studies of cationic lanthanide complexes bearing a phenanthridinium group [J].
Bobba, G ;
Kean, SD ;
Parker, D ;
Beeby, A ;
Baker, G .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (09) :1738-1741
[5]  
Brandes S, 1996, B SOC CHIM FR, V133, P65
[6]   Experimental assessment of lanthanide ion donor preference:: spectroscopic and theoretical dissection of static charge and dynamic polarisation contributions to axial ligation in a C4-symmetric chiral europium complex [J].
Bruce, JI ;
Parker, D ;
Tozer, DJ .
CHEMICAL COMMUNICATIONS, 2001, (21) :2250-2251
[7]   SYNTHESIS OF SOME 2,9-DISUBSTITUTED-1,10-PHENANTHROLINES [J].
CHANDLER, CJ ;
DEADY, LW ;
REISS, JA .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (03) :599-601
[8]   Picosecond time-resolved resonance Raman probing of the light-switch states of [Ru(Phen)2dppz]2+ [J].
Coates, CG ;
Olofsson, J ;
Coletti, M ;
McGarvey, JJ ;
Önfelt, B ;
Lincoln, P ;
Norden, B ;
Tuite, E ;
Matousek, P ;
Parker, AW .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (50) :12653-12664
[9]   DNA binding of ruthenium tris(1,10-phenanthroline): Evidence for the dependence of binding mode on metal complex concentration [J].
Coggan, DZM ;
Haworth, IS ;
Bates, PJ ;
Robinson, A ;
Rodger, A .
INORGANIC CHEMISTRY, 1999, 38 (20) :4486-4497
[10]   Binding of the Δ- and Λ-enantiomers of [Ru(dmphen)2dpq]2+ to the hexanucleotide d(GTCGAC)2 [J].
Collins, JG ;
Aldrich-Wright, JR ;
Greguric, ID ;
Pellegrini, PA .
INORGANIC CHEMISTRY, 1999, 38 (24) :5502-5509