Solubilities of dodecylpolyoxyethylene polyoxypropylene ether in Supercritical carbon dioxide

被引:21
作者
Su, BG [1 ]
Lv, XB [1 ]
Yang, YW [1 ]
Ren, QL [1 ]
机构
[1] Zhejiang Univ, Natl Lab Secondary Resources Chem Engn, Hangzhou 310027, Peoples R China
关键词
D O I
10.1021/je0504010
中图分类号
O414.1 [热力学];
学科分类号
摘要
The equilibrium solubilities of two dodecylpolyoxyethylene polyoxypropylene ether nonionic surfactants (A(EO)BmB(PO)(n)) in supercritical carbon dioxide were measured at temperatures ranging from (308 to 328) K and pressures from (13.6 to 32.0) MPa in a stainless steel variable-volume view cell. The experimental data were correlated using a semiempirical model. The calculated results show satisfactory agreement with the experimental data.
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收藏
页码:542 / 544
页数:3
相关论文
共 15 条
[1]   SOLUBILITIES OF SOLIDS AND LIQUIDS OF LOW VOLATILITY IN SUPERCRITICAL CARBON-DIOXIDE [J].
BARTLE, KD ;
CLIFFORD, AA ;
JAFAR, SA ;
SHILSTONE, GF .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1991, 20 (04) :713-756
[2]   Pressure and temperature dependence of the propagation rate coefficient of free-radical styrene polymerization in supercritical carbon dioxide [J].
Beuermann, S ;
Buback, M ;
Isemer, C ;
Lacik, I ;
Wahl, A .
MACROMOLECULES, 2002, 35 (10) :3866-3869
[3]  
Consani K.A., 1990, J SUPERCRIT FLUID, V3, P51, DOI [10.1016/0896-8446(90)90008-A, DOI 10.1016/0896-8446(90)90008-A]
[4]   HOMOGENEOUS NUCLEATION IN SUPERCRITICAL FLUIDS [J].
DEBENEDETTI, PG .
AICHE JOURNAL, 1990, 36 (09) :1289-1298
[5]  
Ghenciu EG, 1998, BIOTECHNOL BIOENG, V58, P572, DOI 10.1002/(SICI)1097-0290(19980620)58:6<572::AID-BIT2>3.0.CO
[6]  
2-F
[7]   AN ACCURATE EQUATION OF STATE FOR CARBON-DIOXIDE [J].
HUANG, FH ;
LI, MH ;
LEE, LL ;
STARLING, KE ;
CHUNG, FTH .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1985, 18 (06) :490-496
[8]   Reverse micelle formation for acceleration of the supercritical fluid extraction of cholesterol from food samples [J].
Jiménez-Carmona, MM ;
de Castro, MDL .
ANALYTICAL CHEMISTRY, 1998, 70 (10) :2100-2103
[9]   Performance of cholesterol oxidase sequestered within reverse micelles formed in supercritical carbon dioxide [J].
Kane, MA ;
Baker, GA ;
Pandey, S ;
Bright, FV .
LANGMUIR, 2000, 16 (11) :4901-4905
[10]  
KIANOUSH KD, 2003, J CHEM ENG DATA, V48, P860