LAS glass-ceramic scaffolds by three-dimensional printing

被引:51
作者
Zocca, Andrea [1 ]
Gomes, Cynthia M. [2 ]
Bernardo, Enrico [1 ]
Mueller, Ralf [3 ]
Guenster, Jens [2 ]
Colombo, Paolo [1 ]
机构
[1] Univ Padua, Dipartimento Ingn Ind, I-35131 Padua, Italy
[2] BAM Fed Inst Mat Res & Testing, Div Ceram Proc & Biomat, D-12203 Berlin, Germany
[3] BAM Fed Inst Mat Res & Testing, Glass Div, D-12489 Berlin, Germany
关键词
Glass ceramics; Porosity; Shaping; Strength; Additive manufacturing; CRYSTALLIZATION; NUCLEATION; KINETICS;
D O I
10.1016/j.jeurceramsoc.2012.12.012
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Highly porous (>60% open porosity) glass-ceramic scaffolds with remarkable mechanical properties (compression strength of similar to 15 MPa) were produced by indirect 3D printing. Precursor glass powders were printed into 3D ordered structures and then heat treated to sinter and develop crystalline phases. The final glass-ceramic contained a beta-spodumene solid solution together with a secondary phase of lithium disilicate. The precision of the printed geometry and the density of the struts in the scaffold depended on several processing parameters (e.g. powder size and flowability, layer thickness) and were improved by increasing the binder saturation and drying time. Two types of powders with different particle size distribution (PSD) and flowability were used. Powders with a larger PSD, could be processed within a wider range of printing parameters due to their good flowability; however, the printing precision and the struts density were lower compared to the scaffolds printed using the powder in a smaller average PSD. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1525 / 1533
页数:9
相关论文
共 42 条
[1]   The effect of TiO2 addition on the crystallization and phase formation in lithium aluminum silicate (LAS) glasses nucleated by P2O5 [J].
Arvind, A. ;
Sarkar, A. ;
Shrikhande, V. K. ;
Tyagi, A. K. ;
Kothiyal, G. P. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (11) :2622-2627
[2]   THE MECHANICAL-PROPERTIES OF CELLULAR SOLIDS [J].
ASHBY, MF .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1983, 14 (09) :1755-1769
[3]  
Baldi G, 2008, Canada pate publication, Patent No. [CA 2663136 A1, 2663136]
[4]   3D printing of bone substitute implants using calcium phosphate and bioactive glasses [J].
Bergmann, Christian ;
Lindner, Markus ;
Zhang, Wen ;
Koczur, Karolina ;
Kirsten, Armin ;
Telle, Rainer ;
Fischer, Horst .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2010, 30 (12) :2563-2567
[5]   Printability of calcium phosphate powders for three-dimensional printing of tissue engineering scaffolds [J].
Butscher, Andre ;
Bohner, Marc ;
Roth, Christian ;
Ernstberger, Annika ;
Heuberger, Roman ;
Doebelin, Nicola ;
von Rohr, Philipp Rudolf ;
Mueller, Ralph .
ACTA BIOMATERIALIA, 2012, 8 (01) :373-385
[6]   In praise of pores [J].
Colombo, Paolo .
SCIENCE, 2008, 322 (5900) :381-383
[7]   Microstructure and properties of LZSA glass-ceramic foams [J].
de Sousa, E. ;
Rambo, C. R. ;
Hotza, D. ;
de Oliveira, A. P. Novaes ;
Fey, T. ;
Greil, P. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 476 (1-2) :89-97
[8]  
Fuller WB., 1907, Trans Am Soc Civ Eng, V59, P67, DOI DOI 10.1061/TACEAT.0001979
[9]   Dielectric properties of PZT aerogels [J].
Geis, S ;
Löbmann, P ;
Seifert, S ;
Fricke, J .
FERROELECTRICS, 2000, 241 (1-4) :75-82
[10]  
Gildenhaar R., 2012, Key Engineering Materials, V493-494, P849, DOI 10.4028/www.scientific.net/KEM.493-494.849