Radical reaction of the dimethacrylic ester of (2R,4R)-2,4-pentanediol. Addition-cyclization-termination process of high yield under rigorous stereocontrol of the termination step

被引：6

作者：

Sugimura, T

Nagano, S

Tai, A

机构：

[1] Faculty of Science, Himeji Institute of Technology, Ako-gun, Hyogo 678-12, Kanaji, Kamigori

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(97)00699-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of the dimethacrylic ester of (2R,4R)-2,4-pentanediol in the presence of thiophenol resulted in intramolecular C-C bond formation and, after desulfurization, diastereomerically pure (4S)-2,2,4-trimethylglutarate ester was obtained in 93.6% for two steps. (C) 1997 Elsevier Science Ltd.

引用

页码：3547 / 3548

页数：2