Preparation and characterization of ordered mesoporous carbons on SBA-15 template

被引:25
作者
Li, ZL [1 ]
Zhang, J [1 ]
Li, Y [1 ]
Guan, YJ [1 ]
Feng, ZC [1 ]
Li, C [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
关键词
D O I
10.1039/b512697e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ordered mesoporous carbons with high surface area were synthesized using SBA-15 as template at different temperatures. In the process, the precursor ferric acetylacetonate serves as the carbon source for nanofiber formation. In comparison with the morphology of carbon nanotube-encapsulated iron prepared without templates, the orientation of the carbon materials is controlled by the pore direction of the template. The microstructures of the mesoporous carbons are strongly dependent on the temperature of synthesis. Higher synthetic temperatures resulted in ordered mesoporous carbons with larger BET surface areas, pore diameters and increased pore volumes.
引用
收藏
页码:1350 / 1354
页数:5
相关论文
共 26 条
[11]   Ordered mesoporous carbons: Implication of surface chemistry, pore structure and adsorption of methyl mercaptan [J].
Kim, DJ ;
Lee, HI ;
Yie, JE ;
Kim, SJ ;
Kim, JM .
CARBON, 2005, 43 (09) :1868-1873
[12]   A synthetic route to ordered mesoporous carbon materials with graphitic pore walls [J].
Kim, TW ;
Park, IS ;
Ryoo, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4375-4379
[13]   Formation of new type of porous carbon by carbonization in zeolite nanochannels [J].
Kyotani, T ;
Nagai, T ;
Inoue, S ;
Tomita, A .
CHEMISTRY OF MATERIALS, 1997, 9 (02) :609-615
[14]   Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors [J].
Lee, J ;
Yoon, S ;
Hyeon, T ;
Oh, SM ;
Kim, KB .
CHEMICAL COMMUNICATIONS, 1999, (21) :2177-2178
[15]   Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures [J].
Lu, AH ;
Kiefer, A ;
Schmidt, W ;
Schüth, F .
CHEMISTRY OF MATERIALS, 2004, 16 (01) :100-103
[16]  
MATSUDA H, 1995, SCIENCE, V268, P1466
[17]   Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation [J].
Ryoo, R ;
Joo, SH ;
Jun, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (37) :7743-7746
[18]   Mesoporous carbon supported Pt and Pt-Sn catalysts for hydrogenation of cinnamaldehyde [J].
Samant, PV ;
Pereira, MFR ;
Figueiredo, JL .
CATALYSIS TODAY, 2005, 102 :183-188
[19]   Barkhausen jumps and related magnetic properties of iron nanowires encapsulated in aligned carbon nanotube bundles [J].
Satishkumar, BC ;
Govindaraj, A ;
Vanitha, PV ;
Raychaudhuri, AK ;
Rao, CNR .
CHEMICAL PHYSICS LETTERS, 2002, 362 (3-4) :301-306
[20]  
Sayari A, 2001, CHEM MATER, V13, P3151, DOI [10.1021/cm011039l, 10.1021/cm0110391]