Preparation and characterization of ordered mesoporous carbons on SBA-15 template

被引：25

作者：

Li, ZL ^{[1
]}

Zhang, J ^{[1
]}

Li, Y ^{[1
]}

Guan, YJ ^{[1
]}

Feng, ZC ^{[1
]}

Li, C ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2006年 / 16卷 / 14期

关键词：

D O I：

10.1039/b512697e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ordered mesoporous carbons with high surface area were synthesized using SBA-15 as template at different temperatures. In the process, the precursor ferric acetylacetonate serves as the carbon source for nanofiber formation. In comparison with the morphology of carbon nanotube-encapsulated iron prepared without templates, the orientation of the carbon materials is controlled by the pore direction of the template. The microstructures of the mesoporous carbons are strongly dependent on the temperature of synthesis. Higher synthetic temperatures resulted in ordered mesoporous carbons with larger BET surface areas, pore diameters and increased pore volumes.

引用

页码：1350 / 1354

页数：5

共 26 条

[1] Liquid-crystal templates for nanostructured metals [J].

Attard, GS ;

Goltner, CG ;

Corker, JM ;

Henke, S ;

Templer, RH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (12) :1315-1317

[2] Purification and characterization of single-wall carbon nanotubes [J].

Chiang, IW ;

Brinson, BE ;

Smalley, RE ;

Margrave, JL ;

Hauge, RH .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06) :1157-1161

[3] Adsorption of organic compounds on porous carbon sorbents [J].

Eltekova, NA ;

Berek, D ;

Novák, I ;

Belliardo, F .

CARBON, 2000, 38 (03) :373-377

[4] Synthesis of ordered nanoporous carbons of tunable mesopore size by templating SBA-15 silica materials [J].

Fuertes, AB .

MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 67 (2-3) :273-281

[5] True microporosity and surface area of mesoporous SBA-15 silicas as a function of synthesis temperature [J].

Galarneau, A ;

Cambon, H ;

Di Renzo, F ;

Fajula, F .

LANGMUIR, 2001, 17 (26) :8328-8335

[6] Organometallic precursor route to carbon nanotubes [J].

Govindaraj, A ;

Rao, CNR .

PURE AND APPLIED CHEMISTRY, 2002, 74 (09) :1571-1580

[7] Ordered mesoporous materials for bioadsorption and biocatalysis [J].

Hartmann, M .

CHEMISTRY OF MATERIALS, 2005, 17 (18) :4577-4593

[8] RAMAN STUDIES OF CARBON NANOTUBES [J].

HIURA, H ;

EBBESEN, TW ;

TANIGAKI, K ;

TAKAHASHI, H .

CHEMICAL PHYSICS LETTERS, 1993, 202 (06) :509-512

[9] Structure and diffusion characterization of SBA-15 materials [J].

Hoang, VT ;

Huang, QL ;

Eic, M ;

Do, TO ;

Kaliaguine, S .

LANGMUIR, 2005, 21 (05) :2051-2057

[10] Structural study of mesoporous MCM-48 and carbon networks synthesized in the spaces of MCM-48 by electron crystallography [J].

Kaneda, M ;

Tsubakiyama, T ;

Carlsson, A ;

Sakamoto, Y ;

Ohsuna, T ;

Terasaki, O ;

Joo, SH ;

Ryoo, R .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (06) :1256-1266

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